A comprehensive review on redox reactions of Co (III), Co (II) and Co (I) forms of cobalamins
(vitamin B12) and their derivatives (cobinamide, cobyrinates) is presented. An influence of …

The inorganic chemistry of the cobalt corrinoids, derivatives of vitamin B 12, is reviewed, with
particular emphasis on equilibrium constants for, and kinetics of, their axial ligand …

Migratory insertions of alkenes into metal–carbon (M–C) bonds are elementary steps in
diverse catalytic processes. In the present work, a radical-type migratory insertion that …

Molecules containing 3d transition metals (TMs) are usually associated with versatile
reactivity, partly due to their complicated electronic structures involving multiple close‐lying …

Vitamins are organic molecules that are essential for the proper functioning of mammalian
cells. Among them, there is only one organometallic molecule: vitamin B 12, a natural cobalt …

Abstract Pythonic Black-box Electronic Structure Tool (PyBEST) represents a fully-fledged
modern electronic structure software package developed at Nicolaus Copernicus University …

Hybrid density functional theory (B3LYP) and density matrix renormalization group (DMRG)
theory have been used to quantitatively compare the degree of ligand noninnocence …

The methylcobalamin cofactor (MeCbl), which is one of the biologically active forms of
vitamin B12, has been the subject of many spectroscopic and theoretical investigations …

Reductive dehalogenation involving cobalamin has been proved to be a promising strategy
for decontamination of the polluted environment. However, cob (I) alamin can act both as a …

We studied the kinetics of reactions of cob (I) alamin and cob (I) inamide with thiosulfate,
sulfite, and dithionite by UV-Visible (UV-Vis) and stopped-flow spectroscopy. We found that …