AJ Frontier, JJ Hernandez - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus The defining feature of the Nazarov cyclization is a 4π-conrotatory electrocyclization, resulting in the stereospecific formation of functionalized …
Y Zhang, Y Chen, M Song, B Tan, Y Jiang… - Journal of the …, 2022 - ACS Publications
Among the famous Daphniphyllum alkaloids family, the calyciphylline A-type subfamily has triggered particular interest from the organic synthesis community in recent years. Here, we …
Abstract Photolabile Protecting Groups (PPGs) are molecular tools used, for example, in photopharmacology for the activation of drugs with light, enabling spatiotemporal control …
L Feng, Y Teng, X Yu, Z Wang, W Rao - Organic Letters, 2023 - ACS Publications
A novel and unprecedented p-toluenesulfonic acid-catalyzed dehydrative Nazarov-type cyclization/C2–N1 bond cleavage cascade reaction of perfluoroalkylated 3-indolyl (2 …
In recent decades there have been significant improvements in the efficiency of synthesis as a result of considerable progress in tandem reactions, cascade transformations and related …
L Li, XQ Zhu, YQ Zhang, HZ Bu, P Yuan, J Chen… - Chemical …, 2019 - pubs.rsc.org
Alkene carbooxygenation has attracted considerable attention over the past few decades as this approach provides an efficient access to various oxygen-containing molecules …
A Milosavljevic, C Holt, AJ Frontier - Chemical Science, 2023 - pubs.rsc.org
The nitrogen-interrupted Nazarov cyclization can be a powerful method for the stereocontrolled synthesis of sp3-rich N-heterocycles. However, due to the incompatibility …
JJ Hernandez, AJ Frontier - Chemical Science, 2022 - pubs.rsc.org
We report a Brønsted acid-catalyzed carbocyclization cascade, featuring condensation of an alcohol/sulfonamide with an aldehyde followed by an intramolecular three-component …
C Holt, G Alachouzos, AJ Frontier - Journal of the American …, 2019 - ACS Publications
In this report, we describe a halo-Prins/aryl halo-Nazarov cyclization strategy that employs readily available starting materials, inexpensive reagents, and convenient reaction …