Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y Xi, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Bioapplications of RAFT polymerization

C Boyer, V Bulmus, TP Davis, V Ladmiral, J Liu… - Chemical …, 2009 - ACS Publications
A living radical polymerization (LRP) is a free radical polymerization that aims at displaying
living character,(ie, does not terminate or transfer and is able to continue polymerization …

Complex polymer architectures via RAFT polymerization: From fundamental process to extending the scope using click chemistry and nature's building blocks

A Gregory, MH Stenzel - Progress in Polymer Science, 2012 - Elsevier
Reversible addition fragmentation chain transfer (RAFT) polymerization has made a huge
impact in macromolecular design. The first block copolymers were described early on …

PEG–peptide conjugates

IW Hamley - Biomacromolecules, 2014 - ACS Publications
The remarkable diversity of the self-assembly behavior of PEG–peptides is reviewed,
including self-assemblies formed by PEG–peptides with β-sheet and α-helical (coiled-coil) …

Telechelic polymers by living and controlled/living polymerization methods

MA Tasdelen, MU Kahveci, Y Yagci - Progress in Polymer Science, 2011 - Elsevier
Telechelic polymers, defined as macromolecules that contain two reactive end groups, are
used as cross-linkers, chain extenders, and important building blocks for various …

Building nanostructures using RAFT polymerization

C Boyer, MH Stenzel, TP Davis - Journal of Polymer Science …, 2011 - Wiley Online Library
Reversible addition fragmentation chain transfer (RAFT) polymerization is one of the most
extensively studied controlled/living radical polymerization methods that has been used to …

Aqueous photoinduced living/controlled polymerization: tailoring for bioconjugation

J Xu, K Jung, NA Corrigan, C Boyer - Chemical Science, 2014 - pubs.rsc.org
We report a photoinduced living polymerization technique able to polymerize a large range
of monomers, including methacrylates, acrylates and acrylamides, in water and biological …

Trehalose glycopolymers for stabilization of protein conjugates to environmental stressors

RJ Mancini, J Lee, HD Maynard - Journal of the American …, 2012 - ACS Publications
Herein, we report the synthesis of trehalose side chain polymers for stabilization of protein
conjugates to environmental stressors. The glycomonomer 4, 6-O-(4-vinylbenzylidene)-α, α …

Diels–Alder cycloaddition‐cycloreversion: a powerful combo in materials design

A Sanyal - Macromolecular Chemistry and Physics, 2010 - Wiley Online Library
Reactive polymers are increasingly becoming materials of wide interest because they offer
solutions to challenges in biomolecular immobilization, drug‐delivery and enzyme …