Perspective—structure and stability of the solid electrolyte interphase on silicon anodes of lithium-ion batteries

J Kim, OB Chae, BL Lucht - Journal of The Electrochemical …, 2021 - iopscience.iop.org
The solid electrolyte interphase (SEI) acts as a protection layer on the surface the anodes of
lithium ion batteries to prevent further electrolyte decomposition. Understanding the …

Towards separator safety of lithium-ion batteries: a review

B Tong, X Li - Materials Chemistry Frontiers, 2024 - pubs.rsc.org
The safety problem of lithium-ion batteries (LIBs) has restricted their further large-scale
application, especially in electrical vehicles. As a key component of LIBs, separators are …

Robust solid/electrolyte interphase (SEI) formation on Si anodes using glyme-based electrolytes

G Yang, S Frisco, R Tao, N Philip, TH Bennett… - ACS Energy …, 2021 - ACS Publications
Silicon (Si) is the most naturally abundant element possessing 10-fold greater theoretical
capacity compared to that of graphite-based anodes. The practicality of implementing Si …

Surface Work Function‐Induced Thermally Vulnerable Solid Electrolyte Interphase Formation on the Negative Electrode for Lithium‐Ion Batteries

CR Lee, HY Jang, HJ Leem, MA Lee… - Advanced Energy …, 2024 - Wiley Online Library
The chemical composition significantly affects the inherent electrical surface properties of
the graphite and SiO electrodes, which further, significantly alters the thermal stability of …

Interface‐Targeting Individually Functionalized Ionic Additive to Construct Stable Interphase on Selective Electrode Surface for Practical Lithium‐Ion Pouch Cells

W Kim, TH Kim, J Yu, YJ Kim, KJ Kim… - Advanced Functional …, 2023 - Wiley Online Library
Individually functionalized cation‐and anion‐based ionic additives are designed to mitigate
the interfacial side reaction occurring on both the positive and negative electrode surfaces …

[HTML][HTML] Evidence for stepwise formation of solid electrolyte interphase in a Li-ion battery

Y Surace, D Leanza, M Mirolo, Ł Kondracki… - Energy Storage …, 2022 - Elsevier
Replacement of graphite with alloying and conversion materials, having high specific
capacity, has emerged as versatile route to increasing the energy density of Li-ion batteries …

Si-alloy negative electrodes for Li-ion batteries

MN Obrovac - Current Opinion in Electrochemistry, 2018 - Elsevier
Highlights•Recent advancements in Si-alloy development for Li-ion batteries are
reviewed.•Material design, binders and electrolytes are all key to Si-alloy utilization.•Careful …

Effect of Water Concentration in LiPF6-Based Electrolytes on the Formation, Evolution, and Properties of the Solid Electrolyte Interphase on Si Anodes

Y Ha, C Stetson, SP Harvey, G Teeter… - … Applied Materials & …, 2020 - ACS Publications
A trace amount of water in an electrolyte is one of the factors detrimental to the
electrochemical performance of silicon (Si)-based lithium-ion batteries that adversely affect …

Interphasial engineering via individual moiety functionalized organosilane single-molecule for extreme quick rechargeable SiO/NCM811 lithium-ion batteries

H Kim, TH Kim, SS Park, MS Kang… - ACS Applied Materials & …, 2021 - ACS Publications
The individual moiety-functionalized organosilane single molecule, that is, 1, 1, 1, 5, 5, 5-
hexamethyl-3-[(trimethylsilyl) oxy]-3-vinyltrisiloxane (TMSV), is investigated as an electrolyte …

Evaluating the effect of electrolyte additive functionalities on NMC622/Si cell performance

Y Ha, TR Martin, S Frisco, L Rynearson… - Journal of the …, 2022 - iopscience.iop.org
Unstable electrode/electrolyte interface is the major cause of degradation for silicon (Si)-
based anodes for lithium (Li)-ion batteries. Development of functional electrolyte additives …