The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Dearomatization reactions have become fundamental chemical transformations in organic
synthesis since they allow for the generation of three-dimensional complexity from two …

Magnesium hydridotriphenylborate [Mg(thf) 6 ][HBPh 3 ] 2 : a versatile hydroboration catalyst -
Chemical Communications (RSC Publishing) DOI:10.1039/C6CC06805G Royal Society of …

Dearomatization of pyridines is a well-established synthetic approach to access piperidines.
Although remarkably powerful, existing dearomatization processes have been limited to the …

Dearomatized N‐heterocycles are an important class of structural motifs for organic
synthesis and chemical biology. The catalytic dearomative reduction of unactivated N …

Base metal catalysis offers an alternative to reactions, which were once dominated by
precious metals in hydrofunctionalization reactions. This review article details the …

We show that a chiral copper hydride (CuH) complex catalyzes C–C bond-forming
dearomatization of pyridines and pyridazines at room temperature. The catalytic reaction …

N-Heterocyclic phosphenium triflates (NHP-OTf) 1 serve as efficient catalysts for the regio-
and chemoselective hydroboration of pyridines under ambient condition with good …

The reaction of LH [L={(ArNH)(ArN)–C= N–C=(NAr)(NHAr)}; Ar= 2, 6-Et2-C6H3] with a
commercially available alane amine adduct (H3Al· NMe2Et) in toluene resulted in the …

Reductive transformations of easily available oxidized matter are at the heart of synthetic
manipulation and chemical valorization. The applications of catalytic hydrofunctionalization …