Diazo compounds, due to their diverse and rich chemical properties, have remained as one
of the major domains in the organic chemistry research for long time. In the past two …

The beauty of cascade reactions to bestow us with cumbersome organic scaffolds has made
them a cutting-edge area of research. Although the planning of cascades may require …

The development of efficient heterogeneous catalysts with multiselectivity (eg, enantio-and
chemoselectivity) has long been sought after but with limited progress being made so far. To …

Multicomponent reactions that involve interception of onium ylides through Aldol, Mannich,
and Michael addition with corresponding bench-stable acceptors have demonstrated broad …

Multifunctionalization from the interception of active intermediates is an attractive synthetic
strategy for the efficient construction of complex molecular scaffolds in an atom and step …

Catalytic oxidative functionalization of alkynes has emerged as an effective method in
synthetic chemistry in recent decades. However, enantioselective transformations via metal …

Herein, we report an achiral dirhodium complex and chiral phosphoric acid cooperatively
catalyzed asymmetric three-component reaction of enynal with alcohol and imine, affording …

The present work demonstrates a CuCl and anionic chiral cobalt (III)‐catalyzed
enantioselective ring‐opening reaction. The small‐size, ligand‐free copper species enabled …

Albeit notable endeavors in enantioselective carbene insertion into X–H bonds (X= C, O, N,
S, Si, B), the catalytic asymmetric P–H insertion reactions still stand for a long-lasting …

An asymmetric para‐C (sp2)− H bond functionalization of alkyl benzene derivatives was
successfully developed via cooperative catalysis of gold and chiral phosphoric acid (CPA) …