Visible-light-activated heteroaryl azoswitches: toward a more colorful future

T Dang, ZY Zhang, T Li - Journal of the American Chemical …, 2024 - ACS Publications
Azobenzenes (Ph-N═ N-Ph) are known as the most widely studied molecular
photoswitches, and the recent rise of azoheteroarenes (Het-N═ N-Ph or Het-N═ N-Het) …

Azoheteroarene and Diazocine Molecular Photoswitches: Self‐Assembly, Responsive Materials and Photopharmacology

A Mukherjee, MD Seyfried… - Angewandte Chemie …, 2023 - Wiley Online Library
Aromatic units tethered with an azo (− N= N−) functionality comprise a unique class of
compounds, known as molecular photoswitches, exhibiting a reversible transformation …

Photocontrolled energy storage in azobispyrazoles with exceptionally large light penetration depths

A Gonzalez, M Odaybat, M Le… - Journal of the …, 2022 - ACS Publications
Azobispyrazole, 4pzMe-5pzH, derivatives with small terminal substituents (Me, Et, i-Pr, and n-
Pr) are reported to undergo facile reversible photoswitching in condensed phases at room …

Degradation of Cyclin-Dependent Kinase 9/Cyclin T1 by optimized microtubule-associated protein 1 light chain 3 beta-recruiting coumarin analogs

Y Zeng, J Xiao, Y Xu, F Wei, L Tian, Y Gao… - Journal of medicinal …, 2023 - ACS Publications
Autophagy is an efficient and attractive protein degradation pathway in addition to the
ubiquitin-proteasome system. Herein, systematic optimization of coumarin analogs linked …

Bistable Aryl Azopyrazolium Ionic Photoswitches in Water

AK Gaur, D Gupta, A Mahadevan… - Journal of the …, 2023 - ACS Publications
We report a new class of arylazopyrazolium-based ionic photoswitches (AAPIPs). These
AAPIPs with different counter ions have been accessed through a modular synthetic …

Thiazolylazopyrazoles as Nonsymmetric Bis‐Heteroaryl Azo Switches: High‐Yield Visible‐Light Photoisomerization and Increased Z‐Isomer Stability by o …

T Dang, D Dong, J Zhang, Y He… - Angewandte Chemie …, 2023 - Wiley Online Library
Following the progress on mono‐heteroaryl azo switches (Het‐N= N‐Ph), a few bis‐
heteroaryl azo switches (Het‐N= N‐Het) have been studied recently, whereas the …

Photocatalytic (3+ 2) dipolar cycloadditions of aziridines driven by visible-light

D Mazzarella, T Bortolato, G Pelosi, L Dell'Amico - Chemical Science, 2024 - pubs.rsc.org
Herein, we document the design and development of a novel (3+ 2) cycloaddition reaction
aided by the activity of an organic photocatalyst and visible light. The process is extremely …

Room-Temperature Copper-Mediated Radiocyanation of Aryldiazonium Salts and Aryl Iodides via Aryl Radical Intermediates

EW Webb, K Cheng, JS Wright, J Cha… - Journal of the …, 2023 - ACS Publications
Radiocyanation is an attractive strategy for incorporating carbon-11 into radiotracer targets,
particularly given the broad scope of acyl moieties accessible from nitriles. Most existing …

Azide–Alkyne “Click” Reaction in Water Using Parts-Per-Million Amine-Functionalized Azoaromatic Cu (I) Complex as Catalyst: Effect of the Amine Side Arm

M Khatua, B Goswami, Kamal, S Samanta - Inorganic Chemistry, 2021 - ACS Publications
A series of Cu (II) complexes, 1–4 and 6, were synthesized through a reaction of amine-
functionalized pincer-like ligands, HL 1, 2, L a, b, and a bidentate ligand L 1 with CuCl2 …

[HTML][HTML] Clickable nanozyme enhances precise colonization of probiotics for ameliorating inflammatory bowel disease

F Dong, L Hao, L Wang, Y Huang - Journal of Controlled Release, 2024 - Elsevier
Convincing evidence suggests that aberrant gut microbiota changes play a critical role in the
progression and pathogenesis of inflammatory bowel disease (IBD). Probiotic therapeutic …