Phosphorus-based organocatalysis encompasses several subfields that have undergone
rapid growth in recent years. This Outlook gives an overview of its various aspects. In …

Abstract β‐Keto amides are a versatile class of compounds that find wide applications in
organic chemistry owing to the juxtaposition of multiple reaction sites within their molecular …

Tertiary phosphines have been recognized as powerful organocatalysts for the Michael
reaction, which is one of the most important atom-economical methods for carbon-carbon …

The enantioselective addition of isoxazolidin-5-ones to the β-carbon of allenoates has been
carried out by using a novel spirobiindane-based quaternary ammonium salt catalyst. This …

An efficient copper-catalyzed three-component 1, 1-alkylmonofluoroalkylation of terminal
alkynes, diazo compounds, and 2-fluoro-1, 3-dicarbonyl compounds for the synthesis of (E) …

3, 4-disubstituted maleimides find wide applications in various pharmacologically active
compounds. This study presents a highly effective approach for synthesizing derivatives of 3 …

A palladium-catalyzed cascade reaction of β′-allenoate adducts with aryl/heteroaryl
carboxamides through a vinylogous elimination/C–H functionalization/intramolecular …

We have developed a phosphine‐catalyzed (4+ 1) annulative rearrangement for the
preparation of 3‐pyrrolines from allenylic carbamates via phosphonium diene intermediates …

An efficient DBU-catalyzed β-addition of α-fluoro nitroalkane compounds to allenoates has
been developed. Both γ-substituted and-unsubstituted allenoates participated in the …

We herein report the asymmetric organocatalytic addition of azlactones to allenoates. Upon
using chiral quaternary ammonium salt catalysts, ie Maruoka's binaphthylbased spirocyclic …