Interrogating the mechanistic features of Ni (I)-mediated aryl iodide oxidative addition using electroanalytical and statistical modeling techniques

T Tang, A Hazra, DS Min, WL Williams… - Journal of the …, 2023 - ACS Publications
While the oxidative addition of Ni (I) to aryl iodides has been commonly proposed in catalytic
methods, an in-depth mechanistic understanding of this fundamental process is still lacking …

Investigating Oxidative Addition Mechanisms of Allylic Electrophiles with Low-Valent Ni/Co Catalysts Using Electroanalytical and Data Science Techniques

T Tang, E Jones, T Wild, A Hazra… - Journal of the …, 2022 - ACS Publications
The catalysis by a π-allyl-Co/Ni complex has drawn significant attention recently due to its
distinct reactivity in reductive Co/Ni-catalyzed allylation reactions. Despite significant …

Halogen Atom Transfer-Induced Homolysis of C–F Bonds by the Excited-State Boryl Radical

J Koo, W Kim, BH Jhun, S Park, D Song… - Journal of the …, 2024 - ACS Publications
A novel reactivity toward C–F bond functionalization has been developed, which could be
designated as fluorine atom transfer (FAT). A photoexcited state of an N-heterocyclic …

Probing Edge/Support Electronic Cooperativity in Single Edge Fe/Co6Se8 Clusters

BS Mitchell, A Chirila, KJ Anderton… - Inorganic …, 2023 - ACS Publications
This study provides insights into the electronic structure of an atomically precise Fe/Co6Se8
cluster and the extent of redox cooperativity between the Fe active site and the noninnocent …

The control and analysis of one-pot multistep reactions by automation and reaction monitoring technologies

J Liu - 2024 - open.library.ubc.ca
The comprehension, control, and optimization of chemical reactions largely depend on the
apt selection of suitable analytical methodologies. For simpler reactions, characterized by …