Fluoride ion complexation and sensing using organoboron compounds

CR Wade, AEJ Broomsgrove, S Aldridge… - Chemical …, 2010 - ACS Publications
Fluoride is often added to drinking water and toothpaste because of its beneficial effects in
dental health. It is also administered in the treatment of osteoporosis. 1 While the beneficial …

Transmetalation of unsaturated carbon nucleophiles from boron-containing species to the mid to late d-block metals of relevance to catalytic C− X coupling reactions …

DV Partyka - Chemical Reviews, 2011 - ACS Publications
Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

Organotrifluoroborates: Another branch of the mighty oak

GA Molander - The Journal of Organic Chemistry, 2015 - ACS Publications
Over the past two decades, organotrifluoroborates have evolved from being chemical
curiosities to important reagents for the elaboration of organic molecules. Aside from their …

Aryl trifluoroborates in Suzuki–Miyaura coupling: the roles of endogenous aryl boronic acid and fluoride

M Butters, JN Harvey, J Jover, AJJ Lennox… - Angewandte …, 2010 - infona.pl
Entscheidender Schritt: Die Biarylkupplung zwischen Aryltrifluorborat und Arylbromid
erfordert die In‐situ‐Hydrolyse des Borreagens. Die Hydrolyseprodukte sind entscheidend …

[18 F]-Group 13 fluoride derivatives as radiotracers for positron emission tomography

K Chansaenpak, B Vabre, FP Gabbaï - Chemical Society Reviews, 2016 - pubs.rsc.org
The field of 18F chemistry is rapidly expanding because of the use of this radionuclide in
radiotracers for positron emission tomography (PET). Until recently, most [18F]-radiotracers …

Base-promoted protodeboronation of 2, 6-disubstituted arylboronic acids

J Lozada, Z Liu, DM Perrin - The Journal of Organic Chemistry, 2014 - ACS Publications
Facile based promoted deboronation of electron-deficient arylboronate esters was observed
for arylboronates containing two ortho electron-withdrawing group (EWG) substituents …

Efficient hydrolysis of organotrifluoroborates via silica gel and water

GA Molander, LN Cavalcanti, B Canturk… - The Journal of …, 2009 - ACS Publications
A general, mild, and efficient method for the hydrolysis of organotrifluoroborates to unveil
boronic acids using silica gel and H2O was developed. This method proved to be tolerant of …

[HTML][HTML] Lewis acid-assisted isotopic 18F-19F exchange in BODIPY dyes: facile generation of positron emission tomography/fluorescence dual modality agents for …

S Liu, TP Lin, D Li, L Leamer, H Shan, Z Li… - Theranostics, 2013 - ncbi.nlm.nih.gov
Positron emission tomography (PET) is a powerful technique for imaging biological
pathways in vivo, particularly those that are key targets in disease processes. In contrast …

From Unorthodox to Established: The Current Status of 18F-Trifluoroborate- and 18F-SiFA-Based Radiopharmaceuticals in PET Nuclear Imaging

V Bernard-Gauthier, JJ Bailey, Z Liu… - Bioconjugate …, 2016 - ACS Publications
Unorthodox 18F-labeling strategies not employing the formation of a carbon-18F bond are
seldom found in radiochemistry. Historically, the formation of a boron-or silicon-18F bond …

Reaction of [18F]Fluoride at Heteroatoms and Metals for Imaging of Peptides and Proteins by Positron Emission Tomography

KR Scroggie, MV Perkins, JM Chalker - Frontiers in Chemistry, 2021 - frontiersin.org
The ability to radiolabel proteins with [18F] fluoride enables the use of positron emission
tomography (PET) for the early detection, staging and diagnosis of disease. The direct …