Electronic structure of corrole derivatives: insights from molecular structures, spectroscopy, electrochemistry, and quantum chemical calculations

A Ghosh - Chemical Reviews, 2017 - ACS Publications
Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

Strategies for corrole functionalization

JFB Barata, MGPMS Neves, MAF Faustino… - Chemical …, 2017 - ACS Publications
This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

Electrochemistry of corroles in nonaqueous media

Y Fang, Z Ou, KM Kadish - Chemical Reviews, 2017 - ACS Publications
This review describes the known electrochemistry of corroles in nonaqueous media from
1980 until the present. The outline of the review is grouped according to the periodic table …

Water oxidation catalysis by mono-and binuclear iron corroles

W Sinha, A Mahammed, N Fridman, Z Gross - ACS Catalysis, 2020 - ACS Publications
Considering the overwhelming importance and involvement of iron in numerous biocatalytic
processes, the scarceness of synthetic iron complexes as water oxidation catalysts (WOCs) …

Spectroelectrochemistry as a powerful technique for porphyrins/corroles derivatives electro-characterization: fundamentals and some examples

B Dozza, BM Rodrigues, I Tisoco, VB de Souza… - Microchemical …, 2022 - Elsevier
Porphyrins and corroles are at the same time very similar and distinct species. Porphyrins
are present in nature and are well known by scientists for almost two centuries (1840) …

Ground-state copper (III) stabilized by N-confused/N-linked corroles: synthesis, characterization, and redox reactivity

YK Maurya, K Noda, K Yamasumi, S Mori… - Journal of the …, 2018 - ACS Publications
Stable square planar organocopper (III) complexes (CuNCC2, CuNCC4, and CuBN)
supported by carbacorrole-based tetradentate macrocyclic ligands with NNNC coordination …

Synthesis, characterization, and reactivities of high valent metal–corrole (M= Cr, Mn, and Fe) complexes

S Mondal, PK Naik, JK Adha, S Kar - Coordination Chemistry Reviews, 2019 - Elsevier
For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are
relatively lower. However, biological systems in various enzymatic reactions rely extensively …

NIR-emissive, singlet-oxygen-sensitizing gold tetra (thiocyano) corroles

K Sahu, S Angeloni, J Conradie, M Villa, M Nayak… - Dalton …, 2022 - pubs.rsc.org
Presented herein are two fully characterized gold tetrathiocyanocorroles representing a
potentially significant new class of NIR-emissive 5d-metallocorroles. The four SCN groups …

Photocatalytic C–H thiocyanation of corroles: development of near-infrared (NIR)-emissive dyes

K Sahu, S Mondal, SM Mobin, S Kar - The Journal of Organic …, 2021 - ACS Publications
A new method of activating corrole macrocycles via an in situ generated SCN radical has
been developed at very mild conditions at room temperature. This photoredox reaction …

Synthesis, characterization, and application of oxo-molybdenum (V)-Corrolato complexes in epoxidation reactions

M Nayak, P Nayak, K Sahu, S Kar - The Journal of Organic …, 2020 - ACS Publications
Sharpless et al. have described, while performing the molybdenum-catalyzed epoxidation
reaction of olefins using alkyl hydroperoxides, that the molybdenum-oxo moiety is an active …