Deep eutectic solvents: A review of fundamentals and applications

BB Hansen, S Spittle, B Chen, D Poe, Y Zhang… - Chemical …, 2020 - ACS Publications
Deep eutectic solvents (DESs) are an emerging class of mixtures characterized by
significant depressions in melting points compared to those of the neat constituent …

Structure and dynamics of monohydroxy alcohols—Milestones towards their microscopic understanding, 100 years after Debye

R Böhmer, C Gainaru, R Richert - Physics Reports, 2014 - Elsevier
In 1913 Debye devised a relaxation model for application to the dielectric properties of water
and alcohols. These hydrogen-bonded liquids continue to be studied extensively because …

Nuclear spin relaxation in viscous liquids: Relaxation stretching of single-particle probes

M Becher, T Körber, A Döß, G Hinze… - The Journal of …, 2021 - ACS Publications
Spin-lattice relaxation rates R 1 (ω, T), probed via high-field and field-cycling nuclear
magnetic resonance (NMR), are used to test the validity of frequency–temperature …

Liquid 1-propanol studied by neutron scattering, near-infrared, and dielectric spectroscopy

P Sillrén, A Matic, M Karlsson, M Koza… - The Journal of …, 2014 - pubs.aip.org
Liquid monohydroxy alcohols exhibit unusual dynamics related to their hydrogen bonding
induced structures. The connection between structure and dynamics is studied for liquid 1 …

[HTML][HTML] Revealing complex relaxation behavior of monohydroxy alcohols in a series of octanol isomers

T Böhmer, T Richter, JP Gabriel, R Zeißler… - The Journal of …, 2023 - pubs.aip.org
We investigate the reorientation dynamics of four octanol isomers with very different
characteristics regarding the formation of hydrogen-bonded structures by means of photon …

Oscillatory shear and high-pressure dielectric study of 5-methyl-3-heptanol

C Gainaru, M Wikarek, S Pawlus, M Paluch… - Colloid and polymer …, 2014 - Springer
Abstract The monohydroxy alcohol 5-methyl-3-heptanol is studied using rheology at ambient
pressure and using dielectric spectroscopy at elevated pressures up to 1.03 GPa. Both …

Isomeric effects in structure formation and dielectric dynamics of different octanols

J Bolle, SP Bierwirth, M Požar, A Perera… - Physical Chemistry …, 2021 - pubs.rsc.org
The understanding of the microstructure of associated liquids promoted by hydrogen-
bonding and constrained by steric hindrance is highly relevant in chemistry, physics, biology …

[HTML][HTML] Tuning the dynamics of imidazolium-based ionic liquids via hydrogen bonding. I. The viscous regime

CA Thomann, P Münzner, K Moch… - The Journal of …, 2020 - pubs.aip.org
Combining results from impedance spectroscopy and oscillatory shear rheology, the present
work focuses on the relation between the mass and charge flows and on how these are …

[HTML][HTML] Communication: Supramolecular structures in monohydroxy alcohols: Insights from shear-mechanical studies of a systematic series of octanol structural …

T Hecksher, B Jakobsen - The Journal of chemical physics, 2014 - pubs.aip.org
A recent study [C. Gainaru, R. Figuli, T. Hecksher, B. Jakobsen, JC Dyre, M. Wilhelm, and R.
Böhmer, Phys. Rev. Lett. 112, 098301 (2014)] of two supercooled monohydroxy alcohols …

Dielectric and Shear Mechanical Spectra of Propanols: The Influence of Hydrogen-Bonded Structures

M Mikkelsen, JP Gabriel… - The Journal of Physical …, 2022 - ACS Publications
We present a dielectric and shear mechanical study of 1-propanol and three
phenylpropanols. Contrary to other monoalcohols, the phenylpropanols do not show a …