Amines are key intermediates in the chemical industry due to their nucleophilic characteristic
which confers a high reactivity to them. Thus, they are key monomers for the synthesis of …

Conspectus Metalloles are derivatives of cyclopentadiene in which the methylene unit is
replaced by a heteroatom, such as S, Se, Te, N, P, As, Sb, Bi, Si, Ge, Sn, B, Al, Ga, and so …

A novel, one-step N-dehydrogenation of amides to enamides is reported. This reaction
employs the unlikely combination of LiHMDS and triflic anhydride, which serves as both the …

Copper-catalyzed coupling reactions have been recognized as one of the most useful
strategies for the formation of C–N bonds. This perspective gives an overview of the recent …

Herein, we reported a protocol to access the enamide via employing carboxylic acid and
alkenyl isocyanate as the precursors promoted by DMAP without involving any metal …

A novel ynamide preactivation strategy enables the use of otherwise incompatible reagents
and allows preparation of α, β‐disubstituted enamides with high regio‐and stereoselectivity …

An unprecedented Pd-catalyzed trans-addition of boronic acids to ynamides has been
reported, giving α, β-disubstituted enamides in high yields with excellent regio-and …

This paper reports that tertiary α-azidyl phenyl ketones can be transformed into enamides by
treatment with FeBr2 at elevated temperature in DMF. The reaction proceeds via 1, 2 …

The first example of Ir (III)-catalyzed C–H activation/cyclization with N-alkoxyamides as
amidation reagents to simultaneously form functionalized thiadiazine 1-oxide derivatives …

A copper-catalyzed electrophilic enamidation starting from alkynes is reported.
Hydrozirconation of an alkyne with the Schwartz reagent forms a vinyl zirconium …