Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Atomic‐precision gold clusters for NIR‐II imaging

H Liu, G Hong, Z Luo, J Chen, J Chang… - Advanced …, 2019 - Wiley Online Library
Abstract Near‐infrared II (NIR‐II) imaging at 1100–1700 nm shows great promise for medical
diagnosis related to blood vessels because it possesses deep penetration and high …

Tailoring Carbon Tails of Ligands on Au52(SR)32 Nanoclusters Enhances the Near-Infrared Photoluminescence Quantum Yield from 3.8 to 18.3%

Y Wang, Z Liu, A Mazumder… - Journal of the …, 2023 - ACS Publications
One of the important factors that determine the photoluminescence (PL) properties of gold
nanoclusters pertain to the surface. In this study, four Au52 (SR) 32 nanoclusters that feature …

Visible to NIR‐II Photoluminescence of Atomically Precise Gold Nanoclusters

Z Liu, L Luo, R Jin - Advanced Materials, 2024 - Wiley Online Library
Atomically precise gold nanoclusters (NCs) have emerged as a new class of precision
materials and attracted wide interest in recent years. One of the unique properties of such …

Atomically tailored gold nanoclusters for catalytic application

T Higaki, Y Li, S Zhao, Q Li, S Li, XS Du… - Angewandte …, 2019 - Wiley Online Library
Recent advances in the synthetic chemistry of atomically precise metal nanoclusters (NCs)
have significantly broadened the accessible sizes and structures. Such particles are well …

Three-orders-of-magnitude variation of carrier lifetimes with crystal phase of gold nanoclusters

M Zhou, T Higaki, G Hu, MY Sfeir, Y Chen, D Jiang… - Science, 2019 - science.org
We report a three-orders-of-magnitude variation of carrier lifetimes in exotic crystalline
phases of gold nanoclusters (NCs) in addition to the well-known face-centered cubic …

The critical number of gold atoms for a metallic state nanocluster: resolving a decades-long question

M Zhou, X Du, H Wang, R Jin - ACS nano, 2021 - ACS Publications
Probing the transition from a metallic state to a molecular state in gold nanoparticles is
fundamentally important for understanding the origin of surface plasmon resonance and the …

Toward the tailoring chemistry of metal nanoclusters for enhancing functionalities

T Higaki, Q Li, M Zhou, S Zhao, Y Li… - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Ultrasmall metal nanoparticles (often called nanoclusters) possess unique
geometrical structures and novel functionalities that are not accessible in conventional …

A mono-cuboctahedral series of gold nanoclusters: photoluminescence origin, large enhancement, wide tunability, and structure–property correlation

Q Li, M Zhou, WY So, J Huang, M Li… - Journal of the …, 2019 - ACS Publications
The origin of the near-infrared photoluminescence (PL) from thiolate-protected gold
nanoclusters (Au NCs,< 2 nm) has long been controversial, and the exact mechanism for the …