Studies of the local structures of molten metal halides

AL Rollet, M Salanne - Annual Reports Section" C"(Physical Chemistry …, 2011 - pubs.rsc.org
This review covers the local structure of molten metal halide, where a somewhat wide
definition of “local structure” is employed, ie from the first shell of interacting neighbours up …

Temperature and anion ligand field dependence of LnCl3 (Ln= Nd, Dy, Sm) electronic absorption spectra in LiCl–KCl eutectic molten salt

J Moon, J Fuller, Q An, D Chidambaram - Progress in Nuclear Energy, 2023 - Elsevier
A comprehensive knowledge of the coordination, bonding, and speciation of elements in
molten salt mixtures is necessary to understand and predict the chemical and physical …

[图书][B] Physico-chemical analysis of molten electrolytes

V Danek - 2006 - books.google.com
Physico-Chemical Analysis of Molten Electrolytes includes selected topics on the
measurement and evaluation of physico-chemical properties of molten electrolytes. It …

Electrochemical and spectrophotometric study on neodymium ions in molten alkali chloride mixtures

K Fukasawa, A Uehara, T Nagai, T Fujii… - Journal of Alloys and …, 2011 - Elsevier
The thermodynamic stability of Nd (III) complex in various molten alkali chlorides at 923K
was studied by electrochemical analysis. The standard Gibbs free energy change of the …

Raman spectroscopy and quantum chemical calculation on SmCl3-KCl-LiCl molten salt system

C Xu, X Hu, J Yu, P Li, A Liu, S Luo, Z Shi… - Journal of Molecular …, 2024 - Elsevier
The study on the ionic structure of SmCl 3-KCl-LiCl molten systems is of guiding significance
for the practical production of metal samarium and samarium alloys via Molten salt …

Electronic absorption spectra of lanthanides in a molten chloride: II. Absorption characteristics of neodymium (III) in various molten chlorides

T Fujii, T Nagai, N Sato, O Shirai, H Yamana - Journal of alloys and …, 2005 - Elsevier
Electronic absorption spectra of trivalent neodymium in LiCl–KCl eutectic, NaCl–2CsCl
eutectic, CaCl2, LiCl, CsCl and mixtures of these at various temperatures were measured …

Local structure and dynamics of ions in LiCl-GdCl3, KCl-GdCl3 and LiCl-GdCl3-Gd2O3 melts: Ab initio molecular dynamics simulations and Raman spectroscopy

ID Zakiryanova, DO Zakiryanov… - Journal of Molecular …, 2023 - Elsevier
Currently, the novel technologies of gadolinium electrochemical production from raw oxide
materials using molten oxide-salt media are being developed. To understand the …

Electronic absorption spectra of lanthanides in a molten chloride: III. Absorption characteristics of trivalent samarium, dysprosium, holmium, and erbium in various …

T Fujii, T Nagai, A Uehara, H Yamana - Journal of alloys and compounds, 2007 - Elsevier
Electronic absorption spectra of trivalent samarium, dysprosium, holmium, and erbium in
LiCl–KCl eutectic, NaCl–2CsCl eutectic, and mixtures of LiCl and CsCl were measured. The …

Electronic absorption spectra of rare earth (III) species in NaCl–2CsCl eutectic based melts

VA Volkovich, AB Ivanov, SM Yakimov… - AIP Conference …, 2016 - pubs.aip.org
Electronic absorption spectra of ions of trivalent rare earth elements were measured in the
melts based on NaCl–2CsCl eutectic in the wavelength ranges of 190–1350 and 1450 …

Electrochemical and spectrophotometric study on trivalent neodymium ion in molten binary mixtures of LiCl and alkali earth chlorides

K Fukasawa, A Uehara, T Nagai, T Fujii… - Journal of nuclear …, 2011 - Elsevier
The thermodynamic stability of Nd (III) complexes was studied by electrochemical
techniques for molten binary mixtures composed of LiCl and an alkali earth chloride, CaCl 2 …