Technetium-99, a β-emitter produced from 235U fission, poses a challenge for the nuclear
industry due to co-extraction of pertechnetate (TcO4–) with the actinides (An) during nuclear …

The synthesis and solution and solid-state characterization of [Pu4+ (NPC) 4], 1-
Pu,(NPC=[NP t Bu (pyrr) 2]−; t Bu= C (CH3) 3; pyrr= pyrrolidinyl) and [Pu3+ (NPC) 4][K (2.2 …

Amidate-based ligands (N-(tert-butyl) isobutyramide, ITA) bind κ2 to form homoleptic, 8-
coordinate complexes with tetravalent 237Np (Np (ITA) 4, 1-Np) and 242Pu (Pu (ITA) 4, 1 …

A cerium–oxo nanocluster capped by chloride ligands,[CeIV38–n CeIII n O56–(n+ 1)(OH) n+
1Cl51 (H2O) 11] 10–(n= 1–24), has been isolated from acidic chloride solutions by using …

The development of high efficiency and low-temperature molten salt electrolysis methods
can solve the difficulties of poor operation, high equipment requirements, and high cost of …

Abstract Uranium (IV) complexation by 2‐furoic acid (2‐FA) was examined to better
understand the effects of ligand identity and reaction conditions on species formation and …

The solution-state interactions between octadentate hydroxypyridinone (HOPO) and
catecholamide (CAM) chelating ligands and uranium were investigated and characterized …

Structural investigations of three actinide (IV) 4-phosphoryl 1H-pyrazol-5-olate complexes
(An= Th (IV), U (IV), Np (IV)) and their cerium (IV) analogue display the same metal …

Speciation of hexachloride tetravalent uranium, neptunium, and plutonium species in
aqueous media has been investigated using density functional theory in the presence of …

A series of fifteen tetravalent thorium phases were prepared. The compounds were isolated
from acidic aqueous nitrate solutions using protonated nitrogen heterocycles of varying …