Molecular mass spectrometry continues to show an exponential growth, with a substantial
proportion of its applications still requiring the identification of unknown mass spectra. The …

The C–H functionalization of silyl ethers via carbene-induced C–H insertion represents an
efficient synthetic disconnection strategy. In this work, site-and stereoselective C (sp3)–H …

Although it has been known for many years that resonance integrals between hybrid AOs of
a given atom do not vanish, the chemical significance of this has only recently been …

Gas-phase ion-molecule reactions of OsO „+(= 0-4) with a number of hydrocarbons and
small molecules, including CH4, C2H4, C2H6, C3H8, C4Hio, H2, CO, NH3, and SiH4 …

A CuI catalyst (1), supported by a framework of strongly basic guanidinato moieties,
mediates nitrene-transfer from PhI NR sources to a wide variety of aliphatic hydrocarbons …

Ab initio molecular orbital theory with the inclusion of electron correlation using Moller-
Plesset perturbation theory has been applied to study the structures and energetics of Q-C3 …

Recent developments in the field of photoelectron spectroscopy (pes) of transient species
are reviewed. An outline is given of the basic apparatus necessary for such studies and …

The detection and characterization of free organic radicals has been one of the most
important challenges for mass spectrometry during the past 60 years, and, for decades, free …

Adaptation of a low-pressure flat flame burner with a flame-sampling interface to the imaging
photoelectron photoion coincidence spectrometer (iPEPICO) of the VUV beamline at the …

Small carbocations are of longstanding interest in mass spectrometry, organic chemistry and
astrophysics, but there are few measurements of their spectroscopy in the gas phase. Of …