Selective hydrogenation of phenol
The selective hydrogenation of phenol to cyclohexanone has attracted a great deal of
attention both in industry and academia. In this review, the significance, strategies and …
attention both in industry and academia. In this review, the significance, strategies and …
Controlled growth of ultrafine metal nanoparticles mediated by solid supports
As a unique class of nanomaterials with a high surface-area-to-volume ratio and narrow size
distribution, ultrafine metal nanoparticles (UMNPs) have shown exciting properties in many …
distribution, ultrafine metal nanoparticles (UMNPs) have shown exciting properties in many …
High-efficiency electrochemical hydrodeoxygenation of bio-phenols to hydrocarbon fuels by a superacid-noble metal particle dual-catalyst system
Electrocatalytic hydrogenation (ECH) provides a “green” route to upgrade oxygenated bio-
oil under mild conditions, but is still challenged with the issues of low working current density …
oil under mild conditions, but is still challenged with the issues of low working current density …
Mechanistic insights into the pathways of phenol hydrogenation on Pd nanostructures
Product selectivity in aqueous phase phenol hydrogenation on well-defined supported Pd
nanostructures (spheres, cubes, and octahedra) was studied using defined experiments and …
nanostructures (spheres, cubes, and octahedra) was studied using defined experiments and …
Space-confined carbon-doped Pd nanoparticles as a highly efficient catalyst for selective phenol hydrogenation
Q Yu, J Zhou, W Wang, DC Li, X Sun, GH Wang - ACS Catalysis, 2023 - ACS Publications
Pd-based catalysts have been widely applied in hydrogenation reactions for production of
both bulk and fine chemicals; however, selective and efficient hydrogenation of substrates …
both bulk and fine chemicals; however, selective and efficient hydrogenation of substrates …
A Pd/monolayer titanate nanosheet with surface synergetic effects for precise synthesis of cyclohexanones
A catalyst composed of monolayer nonstoichiometric titanate nanosheets (denoted as TN)
and Pd clusters is constructed for precise synthesis of cyclohexanone from phenol …
and Pd clusters is constructed for precise synthesis of cyclohexanone from phenol …
Selective hydrogenation of phenol to cyclohexanone over small amount of Ru-promoted Pd/ZrHP catalysts
Z Wang, B Ye, R Zhou, Z Zhong, P Chen… - Applied Catalysis A …, 2023 - Elsevier
Selective hydrogenation of phenol to cyclohexanone is a vital step in the manufacture of
fiber (nylon), which is currently carried out over expensive Pd catalyst with low productivity …
fiber (nylon), which is currently carried out over expensive Pd catalyst with low productivity …
Selective hydrogenation of phenol to cyclohexanone by SiO2-supported rhodium nanoparticles under mild conditions
A silica-supported rhodium catalyst for the selective hydrogenation of phenol to
cyclohexanone under mild conditions has been developed. As the Rh concentration on the …
cyclohexanone under mild conditions has been developed. As the Rh concentration on the …
Relating the performances of selective phenol hydrogenation with encapsulated palladium nanoparticles and surrounding distinct LTL-zeolite microenvironments
C Liu, J Wang, P Zhu, H Liu, X Zhang - Chemical Engineering Journal, 2022 - Elsevier
Cyclohexanone, as a significant raw material in the production of nylon 6 and nylon 66, is
preferentially synthesized via selective phenol hydrogenation while the key point is to …
preferentially synthesized via selective phenol hydrogenation while the key point is to …
NHC-stabilised Rh nanoparticles: Surface study and application in the catalytic hydrogenation of aromatic substrates
Abstract New Rh-NPs stabilised by N-Heterocyclic Carbenes (NHC) were synthesized by
decomposition of [Rh (η 3-C 3 H 5) 3] under H 2 atmosphere and fully characterized. Surface …
decomposition of [Rh (η 3-C 3 H 5) 3] under H 2 atmosphere and fully characterized. Surface …