[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

N− H and C− H functionalization of sulfoximine: recent advancement and prospects

P Ghosh, B Ganguly, S Das - Asian Journal of Organic …, 2020 - Wiley Online Library
Sulfoximine and its congeners are a versatile class of structural motifs widely found in a
plethora of pharmaceutical compounds and crop protection industries due to their …

Cationic gemini-surfactants based on waste cooking oil as new 'green'inhibitors for N80-steel corrosion in sulphuric acid: A combined empirical and theoretical …

MM Khalaf, AH Tantawy, KA Soliman… - Journal of Molecular …, 2020 - Elsevier
The objective of this report is to investigate the inhibition of cationic gemini-surfactants
based on waste cooking, as a green source of inhibitors against acidic corrosion of N80 …

Enantioselective Synthesis of Chiral‐at‐Sulfur 1,2‐Benzothiazines by CpxRhIII‐Catalyzed C−H Functionalization of Sulfoximines

Y Sun, N Cramer - Angewandte Chemie International Edition, 2018 - Wiley Online Library
Sulfoximines with stereogenic sulfur atoms are attractive structural motifs in drug discovery.
A direct catalytic enantioselective method for the synthesis of sulfur‐chiral 1, 2 …

Efficient Kinetic Resolution of Sulfur‐Stereogenic Sulfoximines by Exploiting CpXRhIII‐Catalyzed C−H Functionalization

M Brauns, N Cramer - Angewandte Chemie, 2019 - Wiley Online Library
Chiral sulfoximines with stereogenic sulfur atoms are promising motifs in drug discovery. We
report an efficient method to access chiral sulfoximines through a C− H functionalization …

para-Selective C–H Olefination of Aniline Derivatives via Pd/S,O-Ligand Catalysis

K Naksomboon, J Poater, FM Bickelhaupt… - Journal of the …, 2019 - ACS Publications
Herein we report a highly para-selective C–H olefination of aniline derivatives by a Pd/S, O-
ligand-based catalyst. The reaction proceeds under mild reaction conditions with high …

Visible‐light‐induced palladium‐catalyzed generation of aryl radicals from aryl triflates

M Ratushnyy, N Kvasovs, S Sarkar… - Angewandte Chemie …, 2020 - Wiley Online Library
A mild visible‐light‐induced Pd‐catalyzed intramolecular C− H arylation of amides is
reported. The method operates by cleavage of a C (sp2)− O bond, leading to hybrid aryl Pd …

Nickela‐electrocatalyzed C− H Alkoxylation with Secondary Alcohols: Oxidation‐Induced Reductive Elimination at Nickel (III)

SK Zhang, J Struwe, L Hu… - Angewandte Chemie …, 2020 - Wiley Online Library
Nickela‐electrooxidative C− H alkoxylations with challenging secondary alcohols were
accomplished in a fully dehydrogenative fashion, thereby avoiding stoichiometric chemical …

Rhoda‐Electrocatalyzed Bimetallic C−H Oxygenation by Weak O‐Coordination

X Tan, L Massignan, X Hou, J Frey… - Angewandte Chemie …, 2021 - Wiley Online Library
Rhodium‐electrocatalyzed arene C− H oxygenation by weakly O‐coordinating amides and
ketones have been established by bimetallic electrocatalysis. Likewise, diverse …

Pd-Catalyzed Ortho C–H Hydroxylation of Benzaldehydes Using a Transient Directing Group

XY Chen, S Ozturk, EJ Sorensen - Organic letters, 2017 - ACS Publications
The direct Pd-catalyzed ortho C–H hydroxylation of benzaldehydes was achieved using 4-
chloroanthranilic acid as the transient directing group, 1-fluoro-2, 4, 6-trimethylpyridnium …