Photochemical and electrochemical strategies towards benzylic C− H functionalization: a recent update

M Oliva, GA Coppola… - Advanced Synthesis …, 2021 - Wiley Online Library
Transition metal‐catalysed processes have been widely used for the functionalization of
inert C− H bonds. Strategies for the functionalization of the benzylic C− H position having a …

Journey describing applications of oxone in synthetic chemistry

H Hussain, IR Green, I Ahmed - Chemical reviews, 2013 - ACS Publications
The existence of a peroxygen acid of sulfur was recognized nearly one and half centuries
ago, 1, 2 but it was not until 1898 that Caro 3 demonstrated the existence of two such acids …

Main group redox catalysis of organopnictogens: vertical periodic trends and emerging opportunities in group 15

JM Lipshultz, G Li, AT Radosevich - Journal of the American …, 2021 - ACS Publications
A growing number of organopnictogen redox catalytic methods have emerged—especially
within the past 10 years—that leverage the plentiful reversible two-electron redox chemistry …

New trends in bismuth-catalyzed synthetic transformations

T Ollevier - Organic & Biomolecular Chemistry, 2013 - pubs.rsc.org
This review covers uses of bismuth catalysts since 2005 with a special emphasis on the
emerging applications of such catalysts. Low toxicity, low catalytic loading, synergistic effects …

Applications of bismuth (III) compounds in organic synthesis

JM Bothwell, SW Krabbe, RS Mohan - Chemical Society Reviews, 2011 - pubs.rsc.org
This review article summarizes the applications of bismuth (III) compounds in organic
synthesis since 2002. Although there are an increasing number of reports on applications of …

Transition Metal‐Free Iodosobenzene‐Promoted Direct Oxidative 3‐Arylation of Quinoxalin‐2(H)‐ones with Arylhydrazines

S Paul, JH Ha, GE Park, YR Lee - Advanced Synthesis & …, 2017 - Wiley Online Library
A transition metal‐free iodosobenzene‐promoted direct oxidative 3‐arylation of quinoxalin‐
2 (H)‐ones was developed using various arylhydrazines under air. The protocol affords a …

Iron‐Catalyzed Benzylic Oxidation with Aqueous tert‐Butyl Hydroperoxide

M Nakanishi, C Bolm - Advanced Synthesis & Catalysis, 2007 - Wiley Online Library
Ironâ•’Catalyzed Benzylic Oxidation with Aqueous <i>tert</i>â•’Butyl Hydroperoxide Page 1
DOI: 10.1002/adsc.200600553 Iron-Catalyzed Benzylic Oxidation with Aqueous tert-Butyl …

Accessing Drug Metabolites via Transition‐Metal Catalyzed C− H Oxidation: The Liver as Synthetic Inspiration

J Genovino, D Sames, LG Hamann… - Angewandte Chemie …, 2016 - Wiley Online Library
Can classical and modern chemical C− H oxidation reactions complement biotransformation
in the synthesis of drug metabolites? We have surveyed the literature in an effort to try to …

Direct and selective benzylic oxidation of alkylarenes via C–H abstraction using alkali metal bromides

K Moriyama, M Takemura, H Togo - Organic letters, 2012 - ACS Publications
A direct benzylic oxidation of alkylarenes via C–H bond abstraction was developed using
alkali metal bromides and oxidants under mild conditions. This reaction proceeded with …

Chloroacetate‐promoted selective oxidation of heterobenzylic methylenes under copper catalysis

J Liu, X Zhang, H Yi, C Liu, R Liu… - Angewandte Chemie …, 2015 - Wiley Online Library
The efficient selective oxidation and functionalization of C H bonds with molecular oxygen
and a copper catalyst to prepare the corresponding ketones was achieved with ethyl …