Functional naphthalene diimides: synthesis, properties, and applications

M Al Kobaisi, SV Bhosale, K Latham… - Chemical …, 2016 - ACS Publications
This comprehensive review surveys developments over the past decade in the field of
naphthalene diimides (NDIs). It explores their application toward: supramolecular chemistry; …

Electron-poor arylenediimides

S Kumar, J Shukla, Y Kumar… - Organic Chemistry …, 2018 - pubs.rsc.org
Arylenediimides are inherently electron deficient and provide enormous opportunities to
conjugate electron withdrawing substituents in different regions of the π-scaffold. This review …

Extraordinary stability of naphthalenediimide radical ion and its ultra-electron-deficient precursor: strategic role of the phosphonium group

S Kumar, MR Ajayakumar, G Hundal… - Journal of the …, 2014 - ACS Publications
Stabilization of radical ions and highly electron-deficient systems under ambient conditions
is of great significance. A new design concept is presented that applies the multifaceted …

Electrically driven white light emission from intrinsic metal–organic framework

G Haider, M Usman, TP Chen, P Perumal, KL Lu… - ACS …, 2016 - ACS Publications
Light-emitting diodes (LEDs) have drawn tremendous potential as a replacement of
traditional lighting due to its low-power consumption and longer lifetime. Nowadays, the …

Potential third-order nonlinear optical response facilitated by intramolecular charge transfer in a simple schiff base molecule: experimental and theoretical exploration

S Kamaal, M Mehkoom, A Ali, SM Afzal, MJ Alam… - ACS …, 2021 - ACS Publications
A Schiff base, namely, 4-[(2-hydroxy-3-methoxybenzylidene) amino] benzoic acid (L1), has
been synthesized by the condensation reaction. It has been characterized by Fourier …

Core-modified naphthalenediimides generate persistent radical anion and cation: New panchromatic NIR probes

MR Ajayakumar, D Asthana, P Mukhopadhyay - Organic letters, 2012 - ACS Publications
The generation of the first persistent radical cation of naphthalenediimide with Cu2+/Fe3+
under ambient conditions is reported. An alternate anionic trigger generates a persistent …

Synthesis of functionalized naphthalene diimides and their redox properties

J Shukla, P Mukhopadhyay - European Journal of Organic …, 2019 - Wiley Online Library
In this article, we have discussed the recently developed synthetic routes to amplify the
electron‐poor nature of the naphthalenediimides (NDIs) as well as the integration of electron …

D− π–A compounds with tunable intramolecular charge transfer achieved by incorporation of butenolide nitriles as acceptor moieties

C Moreno-Yruela, J Garín, J Orduna… - The Journal of …, 2015 - ACS Publications
Chromophores where a polyenic spacer separates a 4 H-pyranylidene or
benzothiazolylidene donor and three different butenolide nitriles have been synthesized and …

Extended tetrathiafulvalenes with polycyclic aromatic cores

O Hammerich, MB Nielsen - Journal of Materials Chemistry C, 2019 - pubs.rsc.org
Redox-active organic molecules have found interest in various areas of materials chemistry,
from organic conductors, electrochromic materials, sensors, to constituents of molecular …

Single electron transfer-driven multi-dimensional signal read-out function of TCNQ as an “Off-the-Shelf” detector for cyanide

MR Ajayakumar, K Mandal, K Rawat… - … Applied Materials & …, 2013 - ACS Publications
Herein we report the first applications of TCNQ as a rapid and highly sensitive off-the-shelf
cyanide detector. As a proof-of-concept, we have applied a kinetically selective single …