Hydride transfer (HT) is a fundamental step in a wide range of reaction pathways, including
those mediated by dihydropyridinates (DHP− s). Coordination of ions directly to the pyridine …

Conspectus Aluminum is the most abundant metal in the earth's crust at 8%, and it is also
widely available domestically in many countries worldwide, which ensures a stable supply …

Coordination of the redox-active tridentate NNO ligand L H2 to PdII yields the paramagnetic
iminobenzosemiquinonato complex 3. Single-electron reduction of 3 yields diamagnetic …

The synthesis, spectroelectrochemical characterization (ultraviolet–visible and nuclear
magnetic resonance), solid state structures, and computational metric parameters of three …

The mechanism by which [Al (salen)] 2O complexes catalyse the synthesis of cyclic
carbonates from epoxides and carbon dioxide in the absence of a halide cocatalyst has …

The reactions of H2AlCl with [(dpp-Bian) Na (Et2O) n] and [(ArBIG-Bian) Na (THF)] produce
respective aluminum hydrides supported by radical-anionic 1, 2-bis (arylimino) …

Metal ions with radical centers in their coordination sphere are key participants in biological
and catalytic processes. In the present study, we describe the synthesis of the cAAC: ZnCl2 …

The reaction of dialane [LAl‐AlL](1; L= dianion of 1, 2‐bis [(2, 6‐diisopropylphenyl) imino]
acenaphthene, dpp‐bian) with carbon dioxide results in two different products depending on …

N-alkylation and N-metallation of pyridine are explored herein to understand how metal-
ligand complexes can model NAD+ redox chemistry. Syntheses of substituted …

A new family of low-coordinate Co complexes supported by three redox-noninnocent
tridentate [OCO] pincer-type bis (phenolate) N-heterocyclic carbene (NHC) ligands are …