3H-Phosphaallenes are accessible on a new and facile route and show a fascinating
chemical behavior. The thermally induced rearrangement of Mes* P═ C═ C (H) R′(R′= t …

An organometallic homopolymer containing three different metals per repeating unit was
synthesized from an air-and moisture-stable secondary phosphine bearing ethylferrocene …

The redox behaviour of sterically constrained tricyclic phosphine 3a was investigated by
spectroelectrochemistry. The data suggested a highly negative reduction potential with the …

To build upon our earlier results of heterometallic metallaboranes employing metal
carbonyls, we performed the reaction of nido-[(Cp* Rh) 2 B 3 H 7](1)(nido-1) with [M (CO) 5 …

Here we report a study on the reactivity of the fluorescent air-stable primary phosphine 8-((4-
phosphino) phenyl)-4, 4-dimethyl-1, 3, 5, 7-tetramethyl-2, 6-diethyl-4-bora-3a, 4a-diaza-s …

In continuation of our research in cyclopentadienylalkylphosphane nickel chelates with
secondary phosphane tethers the first cationic representatives of this class of compounds …

An investigation into the electrophilicity of metal free and metal coordinated phosphenium
ions for PC bond formation, particularly phosphine synthesis, has been carried out. Chloride …

This thesis reports the synthesis of novel, air-stable, fluorescent phosphorus-containing
compounds, based on a Bodipy backbone, and their applications in cell imaging and …

Metal carbonyl complexes (MCCs) are potentially useful for a range of biomedical
applications, including cell imaging and bioassay. However, the poor solubility and stability …