Can green chemistry be the right reading key to let organocatalyst design take a step
forward towards sustainable catalysis? What if the intriguing chemistry promoted by more …

Reported here is the development of a class of chiral spirosilabiindane scaffolds by Rh‐
catalyzed asymmetric double hydrosilation, for the first time. Enantiopure SPSiOL …

A new catalytic asymmetric indolization reaction by a desymmetrizing [3+ 2] annulation
strategy is developed. The reaction proceeds via a rhodium-catalyzed enantioposition …

The importance of P-stereogenic heterocycles has been widely recognized with their
extensive use as privileged chiral ligands and bioactive compounds. The catalytic …

Enantio-enriched 9, 10-dihydroacridines are useful chiral N-heterocycles in many aspects;
however, their asymmetric catalytic synthesis is rather challenging, as the stereocenter is …

The incorporation of chirality endows Pt (II)-based metal–organic complexes (MOCs) with
unique potentials in several fields such as nonlinear optics and chiral catalysis. However …

The development of chiral architectures for chiral ligand and catalyst discovery is essential
for asymmetric catalysis. Herein, we report the concise synthesis of a Si-centered spirocyclic …

Privileged chiral catalysts have found tremendous applications and thus immensely
advanced asymmetric synthesis in the past few decades. However, truly privileged chiral …

A family of C 2-symmetrical 1, 1′-spirobiindane-7, 7′-diol (SPINOL) derivatives containing
polymerizable styryl units has been prepared through a highly convergent approach …

A Ag/P-stereogenic phosphine-complex-catalyzed 1, 3-dipolar cycloaddition of azomethine
ylides with electron-deficient olefins is reported. In this reaction, highly functionalized …