Bowls, hoops, and saddles: synthetic approaches to curved aromatic molecules

MA Majewski, M Stępień - Angewandte Chemie International …, 2019 - Wiley Online Library
This review summarizes recent advances in the chemistry of curved aromatic molecules. By
focusing on the key accomplishments of the last decade, we provide a general overview of …

Synthesis and functionalization of porphyrins through organometallic methodologies

S Hiroto, Y Miyake, H Shinokubo - Chemical reviews, 2017 - ACS Publications
This review focuses on the postfunctionalization of porphyrins and related compounds
through catalytic and stoichiometric organometallic methodologies. The employment of …

[HTML][HTML] Macrocyclization reactions: the importance of conformational, configurational, and template-induced preorganization

V Marti-Centelles, MD Pandey, MI Burguete… - Chemical …, 2015 - ACS Publications
Macrocyclic structures are common synthetic targets in drug discovery,(1, 2) and therefore,
interest in their study is continuously increasing in this field.(3, 4) A classic example is …

Template-directed synthesis of molecular nanorings and cages

PS Bols, HL Anderson - Accounts of chemical research, 2018 - ACS Publications
Conspectus This Account is about templates as construction tools: molecules for making
molecules. A template organizes the reactants and provides information to promote …

Increasing the size and complexity of discrete 2D metallosupramolecules

H Wang, Y Li, N Li, A Filosa, X Li - Nature Reviews Materials, 2021 - nature.com
Owing to the reversible, directional and predictable nature of metal–ligand coordination,
coordination-driven self-assembly has emerged as a powerful bottom-up strategy for …

Self-assembly of Russian doll concentric porphyrin nanorings

SAL Rousseaux, JQ Gong, R Haver… - Journal of the …, 2015 - ACS Publications
Electronic communication between concentric macrocycles with wave functions that extend
around their circumferences can lead to remarkable behavior, as illustrated by multiwalled …

Multiporphyrinic architectures: Advances in structural design for photodynamic therapy

Y Gao, Y Li, Z Xu, S Yu, J Liu, H Sun - Aggregate, 2024 - Wiley Online Library
Rationally designed multiporphyrinic architectures for boosting photodynamic therapy (PDT)
have attracted significant attentions recently years due to their great potential for light …

Caterpillar track complexes in template‐directed synthesis and correlated molecular motion

S Liu, DV Kondratuk, SAL Rousseaux… - Angewandte Chemie …, 2015 - Wiley Online Library
Small alterations to the structure of a star‐shaped template totally change its mode of
operation. The hexapyridyl template directs the conversion of a porphyrin dimer to the cyclic …

Schalen, Reifen und Sattel: Methoden zur Synthese gebogener aromatischer Moleküle

MA Majewski, M Stępień - Angewandte Chemie, 2019 - Wiley Online Library
Dieser Aufsatz fast die jüngsten Fortschritte in der Chemie gekrümmter aromatischer
Moleküle zusammen. Mit dem Schwerpunkt auf den wesentlichen Erfolgen des …

Experimental and theoretical evidence for aromatic stabilization energy in large macrocycles

M Jirásek, M Rickhaus, L Tejerina… - Journal of the American …, 2021 - ACS Publications
Enhanced thermodynamic stability is a fundamental characteristic of aromatic molecules, yet
most previous studies of aromatic stabilization energy (ASE) have been limited to small rings …