Bimetallic catalysts for upgrading of biomass to fuels and chemicals

DM Alonso, SG Wettstein, JA Dumesic - Chemical Society Reviews, 2012 - pubs.rsc.org
Research interest in biomass conversion to fuels and chemicals has increased significantly
in the last decade as the necessity for a renewable source of carbon has become more …

Hydrogenolysis goes bio: from carbohydrates and sugar alcohols to platform chemicals

AM Ruppert, K Weinberg… - Angewandte Chemie …, 2012 - Wiley Online Library
In view of the diminishing oil resources and the ongoing climate change, the use of efficient
and environmentally benign technologies for the utilization of renewable resources has …

Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals

CHC Zhou, JN Beltramini, YX Fan… - Chemical Society Reviews, 2008 - pubs.rsc.org
New opportunities for the conversion of glycerol into value-added chemicals have emerged
in recent years as a result of glycerol's unique structure, properties, bioavailability, and …

Environmental and economical perspectives of a glycerol biorefinery

GM Lari, G Pastore, M Haus, Y Ding… - Energy & …, 2018 - pubs.rsc.org
Glycerol conversion into chemicals and fuel additives is pursued to valorise a burgeoning by-
product in the bioenergy sector. To this aim, heterogeneous catalysts have been developed …

Fundamentals of H2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H2 Production and Storage

GJ Kubas - Chemical reviews, 2007 - ACS Publications
Formation of stable iron hydrides on more nucleophilic (electron-rich) metal centers than
those found in hydrogenases with CO ligands would inhibit or at least slow down function …

Brønsted–Lowry acid strength of metal hydride and dihydrogen complexes

RH Morris - Chemical Reviews, 2016 - ACS Publications
Transition metal hydride complexes are usually amphoteric, not only acting as hydride
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …

Renewable chemicals: dehydroxylation of glycerol and polyols

J Ten Dam, U Hanefeld - ChemSusChem, 2011 - Wiley Online Library
The production of renewable chemicals is gaining attention over the past few years. The
natural resources from which they can be derived in a sustainable way are most abundant in …

Glycerol hydrogenolysis on heterogeneous catalysts

J Chaminand, L Aurent Djakovitch, P Gallezot… - Green …, 2004 - pubs.rsc.org
Aqueous solutions of glycerol were hydrogenolysed at 180° C under 80 bar H2-pressure in
the presence of supported metal catalysts in an attempt to selectively produce 1, 2-and 1, 3 …

Glycerol conversion in the aqueous solution under hydrogen over Ru/C+ an ion-exchange resin and its reaction mechanism

T Miyazawa, Y Kusunoki, K Kunimori, K Tomishige - Journal of Catalysis, 2006 - Elsevier
Of the various noble metals (Ru/C, Rh/C, Pt/C, and Pd/C) and acid catalysts [an ion-
exchange resin (Amberlyst), H2SO4 (aq), and HCl (aq)], the combination of Ru/C with …

A review: Conversion of bioglycerol into 1, 3-propanediol via biological and chemical method

CS Lee, MK Aroua, WMAW Daud, P Cognet… - … and Sustainable Energy …, 2015 - Elsevier
Today, the price of glycerol has dramatically dropped due to its oversupply from biodiesel
production as well as oleochemical industry. Thus, it is essential to develop processes to …