Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications

S Hameury, P de Frémont, P Braunstein - Chemical Society Reviews, 2017 - pubs.rsc.org
Ligand design has met with considerable success with both categories of hybrid ligands,
which are characterized by chemically different donor groups, and of N-heterocyclic …

Sulfur-functionalized N-heterocyclic carbenes and their transition metal complexes

M Bierenstiel, ED Cross - Coordination Chemistry Reviews, 2011 - Elsevier
Donor group functionalized N-heterocyclic carbenes (NHC) are an important class of ligands
used in transition metal complex chemistry. Herein, the growing field of sulfur-functionalized …

Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media

S Moret, PJ Dyson, G Laurenczy - Nature communications, 2014 - nature.com
The chemical transformation of carbon dioxide into useful products becomes increasingly
important as CO2 levels in the atmosphere continue to rise as a consequence of human …

Well-defined bis (NHC) Mn (I) complex catalyzed tandem transformation of α, β-unsaturated ketones to α-methylated ketones using methanol

K Ganguli, A Mandal, S Kundu - ACS Catalysis, 2022 - ACS Publications
Tandem transformation of α, β-unsaturated ketones to α-methylated ketones by utilizing
methanol as both the hydrogen and C1 sources is reported in the presence of a phosphine …

Design and development of functionalized cyclometalated ruthenium chromophores for light-harvesting applications

KCD Robson, BD Koivisto, A Yella… - Inorganic …, 2011 - ACS Publications
The syntheses and the electrochemical spectroscopic properties of a suite of asymmetrical
bis tridentate cyclometalated Ru (II) complexes bearing terminal triphenylamine (TPA) …

Rh (I) complexes with hemilabile thioether-functionalized NHC ligands as catalysts for [2+ 2+ 2] cycloaddition of 1, 5-bisallenes and alkynes

J Vila, M Solà, T Achard, S Bellemin-Laponnaz… - ACS …, 2023 - ACS Publications
The [2+ 2+ 2] cycloaddition of 1, 5-bisallenes and alkynes under the catalysis of Rh (I) with
hemilabile thioether-functionalized N-heterocyclic carbene ligands is described. This …

Electronically tuneable orthometalated Ru II–NHC complexes as efficient catalysts for C–C and C–N bond formations via borrowing hydrogen strategy

PM Illam, A Rit - Catalysis Science & Technology, 2022 - pubs.rsc.org
The catalytic activities of a series of simple and electronically tuneable cyclometalated RuII–
NHC complexes (2a–d) were explored in various C–C/N bond formations following the …

Carbene transfer from triazolylidene gold complexes as a potent strategy for inducing high catalytic activity

D Canseco-Gonzalez, A Petronilho… - Journal of the …, 2013 - ACS Publications
A series of gold (I) complexes [AuCl (trz)] were synthesized that contain 1, 2, 3-triazolylidene
(trz) ligands with variable wingtip groups. In the presence of AgBF4, these complexes …

Ruthenium (II) picolyl-NHC complexes: synthesis, characterization, and catalytic activity in amine N-alkylation and transfer hydrogenation reactions

FE Fernandez, MC Puerta, P Valerga - Organometallics, 2012 - ACS Publications
Ruthenium (II) p-cymene complexes with picolyl-functionalized N-heterocyclic carbenes [(η6-
p-cymene) Ru (L)(Cl)][PF6](L= 3-methyl-1-(2-picolyl) imidazol-2-ylidene (1a), 3-isopropyl-1 …

Tunable single-site ruthenium catalysts for efficient water oxidation

L Bernet, R Lalrempuia, W Ghattas… - Chemical …, 2011 - pubs.rsc.org
The catalyticwater oxidation activity of mononuclear ruthenium complexes comprising a
pyridine-functionalized abnormal triazolylidene ligand can be adjusted by modification of the …