We compare viscoelastic properties of several polystyrene solutions and melts with the same number of entanglements. It is demonstrated that the modulus and time can be shifted …
Transient structures based on associative polymers can deliver complex functions; as such, they hold promise for advanced applications as in drug delivery, tissue engineering, and …
The design and effective application of supramolecular transient polymer networks based on the assembly of entangled polymer building blocks requires not only precise description of …
Many of the fascinating properties of natural materials emerge upon phase separation and clustering. However, biomimetic polymeric materials often demonstrate limited performances …
The linear viscoelastic properties of entangled hydrolysed poly (n-butyl acrylate) PnBA copolymers, with varying density of functional moieties, ie, acrylic acid (AA) groups, have …
We carried out molecular dynamics simulations to study the crystallization of long polymers in a concentrated solution made by an explicit solvent of short chains. The weight-averaged …
Understanding the dynamics of polymeric liquids has great importance in the design and processing of soft materials. While slow flow dynamics is now resolved, fast flow dynamics is …
The properties and function of supramolecular polymer networks are determined not only by pairwise interchain transient associations but also by chain entanglement and nanoscopic …
We study the entanglement properties of polyelectrolytes in salt-free and excess-salt solutions, corresponding to rod-like and expanded coil conformations, respectively. While …