Highly efficient FeCl3 doped Mg(OEt)2/TiCl4-based Ziegler–Natta catalysts for ethylene polymerization

R Bazvand, N Bahri-Laleh… - Designed Monomers …, 2015 - Taylor & Francis
Seven Mg (OEt) 2/FeCl3/SiCl4/TiCl4 type procatalysts supported on Mg (OEt) 2/FeCl3
mixtures were prepared in order to unravel effect of Fe doping on the catalytic performance …

Synthesis of highly isotactic poly 1-hexene using Fe-doped Mg(OEt)2/TiCl4/ED Ziegler–Natta catalytic system

F Nouri-Ahangarani, N Bahri-Laleh… - Designed Monomers …, 2016 - Taylor & Francis
In this article, polymerization of 1-hexene with FeCl3-doped Mg (OET) 2/TiCl4/electron
donor (ED) catalytic system is presented. For this purpose, first a number of TiCl4 catalysts …

负载型Ziegler-Natta催化剂的研究进展—MgCl2载体的活化及其对烯烃聚合的影响

范勋章, 罗淑芳, 赵远进, 高文霄, 贺爱华 - 高分子通报, 2024 - gfztb.com
以MgCl 2 作为载体的负载型Ziegler-Natta 催化剂是聚烯烃(特别是聚乙烯, 聚丙烯)
生产的重要催化剂, Ziegler-Natta 催化剂的载体——活化MgCl 2 的结构和形态影响了催化剂 …

Structural investigations of porous MgCl2–2-butanol molecular adduct as support for olefin polymerization

KS Thushara, TG Ajithkumar, PR Rajamohanan… - Applied Catalysis A …, 2014 - Elsevier
A new heterogeneous Ziegler–Natta (Z–N) catalyst support material, MgCl 2· 4 (CH 3 CH
(OH) CH 2 CH 3)(Mg2BuOH) has been synthesized. 2-Butanol, a linear, secondary alcohol …

Effect of alkoxysilanes formed in situ on the properties of Ziegler–Natta catalysts for olefin polymerisation

J Chirinos, J Fernandez, D Perez, T Rajmankina… - Journal of Molecular …, 2005 - Elsevier
TiCl4/MgCl2–alkoxysilane-based catalysts for olefin polymerisation were prepared by
supporting TiCl4 on recrystallised MgCl2 containing grafted alkoxysilane. The alkoxysilanes …

Comparison of Mg-ethoxide based Ziegler Natta catalysts using different internal donors employed for ethylene polymerization

Z Mohamadi, G Moradi, H Teimoury - Journal of Polymer Research, 2021 - Springer
The effect of two types internal electron donors (IDs) on Mg-ethoxide based ZN catalysts
employed for ethylene polymerization, was investigated using three similar catalysts with …

[PDF][PDF] Research progress on supported Ziegler-Natta catalysts—activation of MgCl2 support and its influences on olefin polymerizations

XZ Fan, SF Luo, YJ Zhao, WX Gao, AH He - Polym. Bull - gfztb.com
The supported Ziegler-Natta catalyst utilizing MgCl2 as carrier holds paramount significance
in the synthesis of polyolefins, notably polyethylene and polypropylene. The inherent …

Ethylene polymerization using metallocenes supported on MgCl2/SiCl4− n (n-C6H13O) n

A Morillo, A Parada, D Ibarra, E Passaglia… - Designed monomers …, 2007 - Taylor & Francis
Metallocene complexes Cp2TiCl2, Cp2ZrCl2, Cp2Zr (N n Bu2) 2, Cp2Ti (η 1-OC (O) C6H5)
2 and Cp2Zr (η 1-OC (O) C6H5) 2 were supported on MgCl2/SiCl4− n (n-C6H13O) n carrier …

POSS-modified supported Ziegler-Natta catalyst and its ethylene/1-hexene copolymerization

W Ning, HUI Lei, C Mei, LI Wei, Z Qi - CIESC Journal, 2021 - hgxb.cip.com.cn
Macroporous SiO 2 (Macro-SiO 2) with an open framework structure and MgCl 2 are used to
form a composite carrier, and polysilsesquioxane (POSS) is introduced to form a spatially …

Synthesis of Ziegler-Natta catalysts containing SiCl4/TEOS/TiCl4/MgCl2 for ethylene/1-hexene copolymerization

W Ousirisombat - 2019 - digital.car.chula.ac.th
Polyethylene (PE) is still worldwide manufacturing, and its most productivity is in Asia. The
main categories of PE including high density polyethylene (HDPE), low density polyethylene …