C− C bond formation is a fundamental transformation in organic synthesis. The development
of new synthetic methodology could be considered as a way of pursuing a novel method for …

In this review article, we consider the use of molecular oxygen in reactions mediated by
polyoxometalates. Polyoxometalates are anionic metal oxide clusters of a variety of …

Over the last two decades, transition-metal catalyzed C–H functionalization of indoles has
emerged as an area of extensive research and tremendous progress has been made in this …

The synthetic methodology for direct indole functionalizations is of great significance in
indole chemistry and has been intensively investigated in the last few decades. From the …

The direct introduction of alkenyl groups into the indole framework avoiding its preliminary
functionalization can be carried out using different synthetic strategies. Transition‐metal …

An efficient, atom-economic one-pot method was developed for the preparation of 7-
substituted indoles via rhodium (III)-catalyzed oxidative cross-coupling. Regioselective …

Construction of 3-vinylindoles (3) and β, β-diindolyl propionates (4) through solvent-free C–
H functionalization has been explored under high-speed ball-milling conditions. The …

Efficient control of regioselectivity is a key concern in transition-metal-catalyzed direct C–H
functionalization reactions. Various strategies for regiocontrol have been established by …

Herein, we report the first site-selective, Pd (II)-catalyzed, cross-dehydrogenative Heck
reaction of indoles in micro flow. By use of a capillary microreactor, we were able to boost …

A simple and efficient visible-light-induced intermolecular [3+ 2] alkenylation–cyclization
process has been developed. This reaction provided an unprecedented metal-free double C …