While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …

Iron is the cheapest and one of the most abundant transition metals. Natural [FeFe]‐
hydrogenases exhibit remarkably high activity in hydrogen evolution, but they suffer from …

Solar H2 generation from water has been intensively investigated as a clean method to
convert solar energy into hydrogen fuel. During the past few decades, many studies have …

Triplet photosensitizers (PSs) are compounds that can be efficiently excited to the triplet
excited state which subsequently act as catalysts in photochemical reactions. The name is …

Enzyme mimics or artificial enzymes are a class of catalysts that have been actively pursued
for decades and have heralded much interest as potentially viable alternatives to natural …

The chemical literature often does not differentiate between photocatalytic (PC) and
photosynthetic (PS) processes (including artificial photosynthesis) even though these …

Virtually all organosulfur compounds react with Fe (0) carbonyls to give the title complexes.
These reactions are reviewed in light of major advances over the past few decades, spurred …

This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …

A great technological challenge facing our global future is the development of a secure,
clean, and renewable energy source. 1-4 Rising standards of living in a growing world …