Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

Uranium-containing polyoxometalates (U-POMs), an important class of actinide cluster
compounds, are the products of the assembly of uranium or uranium and POMs. These …

Metal oxide clusters, especially transition-metal polyoxometalates, have been studied for
decades because they provide a rare opportunity to study nanoscale materials with well …

While the d0 transition-metal POMs of Group V (V5+, Nb5+, Ta5+) and Group VI (Mo6+,
W6+) have been known for more than a century, the actinyl peroxide POMs, specifically …

Uranium phosphonates, an important class of actinide-organic coordination polymers,
exhibit an exceptionally diverse and broad range of crystal structures. A variety of structure …

Uranyl peroxide clusters containing from 16 to 124 uranyl ions self-assemble in aqueous
solution and exhibit tremendous topological complexity. Most of these clusters are cages …

In the wide area of polyoxometalate (POM) chemistry, diphosphate/diphosphonate-based
POMs represent a more recent area of study. However, in this short time it has emerged to …

Although the transition d-or 4f-block elements are the most used metals for the construction
of metal–organic frameworks (MOFs), actinide cations were also involved in the elaboration …

Uranyl-peroxide nanoclusters display different topologies based on square, pentagonal and
hexagonal building blocks. Computed complexation energies of different cations (Li+, Na+ …

Giant mixed‐metal clusters have been assembled with the multinuclear silver (I) tert‐
butylethynide supramolecular synthon and phosphonate‐functionalized oxovanadate …