Microgels react to force: mechanical properties, syntheses, and force-activated functions

MF Schulte, E Izak-Nau, S Braun, A Pich… - Chemical Society …, 2022 - pubs.rsc.org
Microgels are colloidal polymer networks with high molar mass and properties between rigid
particles, flexible macromolecules, and micellar aggregates. Their unique stimuli …

Microgels at interfaces, from mickering emulsions to flat interfaces and back

MA Fernandez-Rodriguez, A Martin-Molina… - Advances in colloid and …, 2021 - Elsevier
In this review, we cover the topic of p (NIPAM) based microgels at interfaces, revisiting
classical studies in light of the newest ones. In particular, we focus on their use as …

Interactions between interfaces dictate stimuli-responsive emulsion behaviour

M Rey, J Kolker, JA Richards, I Malhotra… - Nature …, 2023 - nature.com
Stimuli-responsive emulsions offer a dual advantage, combining long-term storage with
controlled release triggered by external cues such as pH or temperature changes. This study …

In-situ study of the impact of temperature and architecture on the interfacial structure of microgels

S Bochenek, F Camerin, E Zaccarelli, A Maestro… - Nature …, 2022 - nature.com
The structural characterization of microgels at interfaces is fundamental to understand both
their 2D phase behavior and their role as stabilizers that enable emulsions to be broken on …

Defined core–shell particles as the key to complex interfacial self-assembly

J Menath, J Eatson, R Brilmayer… - Proceedings of the …, 2021 - National Acad Sciences
The two-dimensional self-assembly of colloidal particles serves as a model system for
fundamental studies of structure formation and as a powerful tool to fabricate functional …

Resolving the different bulk moduli within individual soft nanogels using small-angle neutron scattering

JE Houston, L Fruhner, A de la Cotte… - Science …, 2022 - science.org
The bulk modulus, K, quantifies the elastic response of an object to an isotropic
compression. For soft compressible colloids, knowing K is essential to accurately predict the …

Exploring the 3D Conformation of Hard‐Core Soft‐Shell Particles Adsorbed at a Fluid Interface

J Vialetto, F Camerin, SN Ramakrishna… - Advanced …, 2023 - Wiley Online Library
The encapsulation of a rigid core within a soft polymeric shell allows obtaining composite
colloidal particles that retain functional properties, eg, optical or mechanical. At the same …

Recent advances in cellulose microgels: preparations and functionalized applications

Y Yang, L Sha, H Zhao, Z Guo, M Wu, P Lu - Advances in Colloid and …, 2023 - Elsevier
Microgels are soft, deformable, permeable, and stimuli-responsive microscopic polymeric
particles that are now emerging as prospective multifunctional soft materials for delivery …

Effect of internal architecture on the assembly of soft particles at fluid interfaces

J Vialetto, F Camerin, F Grillo, SN Ramakrishna… - ACS …, 2021 - ACS Publications
Monolayers of soft colloidal particles confined at fluid interfaces are at the core of a broad
range of technological processes, from the stabilization of responsive foams and emulsions …

Two-step deswelling in the Volume Phase Transition of thermoresponsive microgels

G Del Monte, D Truzzolillo, F Camerin… - Proceedings of the …, 2021 - National Acad Sciences
Thermoresponsive microgels are one of the most investigated types of soft colloids, thanks
to their ability to undergo a Volume Phase Transition (VPT) close to ambient temperature …