[HTML][HTML] The known-unknowns of anomalous underscreening in concentrated electrolytes
Electrolytes are central to life and technology but lack complete understanding. Recent
experiments with highly concentrated electrolytes have revealed electrostatic decay lengths …
experiments with highly concentrated electrolytes have revealed electrostatic decay lengths …
Overcoming Debye screening effect in field-effect transistors for enhanced biomarker detection sensitivity
Q Meng, H Li, W Zhao, M Song, W Zhang, X Li, J Chen… - Nanoscale, 2024 - pubs.rsc.org
Field-effect transistor (FET)-based biosensors not only enable label-free detection by
measuring the intrinsic charges of biomolecules, but also offer advantages such as high …
measuring the intrinsic charges of biomolecules, but also offer advantages such as high …
Investigation of the limits of the linearized Poisson–Boltzmann equation
This work presents a comparison between a numerical solution of the Poisson–Boltzmann
equation and the analytical solution of its linearized version through the Debye–Hückel …
equation and the analytical solution of its linearized version through the Debye–Hückel …
[HTML][HTML] Comparisons of equation of state models for electrolytes: e-CPA and e-PPC-SAFT
MD Olsen, GM Kontogeorgis, JC de Hemptinne… - Fluid Phase …, 2023 - Elsevier
Many different models have been published with the aim of describing electrolyte
thermodynamics. In this study two successful Equations of State (EoS) are compared. The …
thermodynamics. In this study two successful Equations of State (EoS) are compared. The …
[HTML][HTML] How to account for the concentration dependency of relative permittivity in the Debye–Hückel and Born equations
This work discusses the introduction of the concentration dependency of relative permittivity
in the context of activity coefficient models at different stages of the derivation of the models …
in the context of activity coefficient models at different stages of the derivation of the models …
Ionization difference between weak and strong electrolytes as perturbed by conductivity spectra analysis
While the static structure of aqueous electrolytes has been studied for decades, their
dynamic microscopic structure remains unresolved yet critical in many areas. We report a …
dynamic microscopic structure remains unresolved yet critical in many areas. We report a …
The Connection between the Debye and Güntelberg Charging Processes and the Importance of Relative Permittivity: The Ionic Cloud Charging Process
The Debye and Güntelberg Charging Processes are essential tools for deriving electrolyte
solutions' activity coefficient models. The Debye–Hückel, Born, and Mean Spherical …
solutions' activity coefficient models. The Debye–Hückel, Born, and Mean Spherical …
[HTML][HTML] The true Hückel equation for electrolyte solutions and its relation with the Born term
In this work we present Hückel's original derivation and considerations, verifying the
approximations that were done in his paper. More complex equations are obtained by not …
approximations that were done in his paper. More complex equations are obtained by not …
[HTML][HTML] Behavior of the aqueous sodium chloride solutions from molecular simulations and theories
Molecular simulations and theories are important tools for studying electrolyte solutions. In
this work, molecular dynamics simulations with one of the most widely used force field …
this work, molecular dynamics simulations with one of the most widely used force field …
[HTML][HTML] Resurrection of Hückel's idea: Decoupling ion–ion and ion–water terms in activity coefficients via the state-dependent dielectric constant
Although Hückel proposed the basic idea of using a concentration dependent dielectric
constant, ϵ (c), to compute the activity coefficients of ions in electrolytes in 1925 (Hückel …
constant, ϵ (c), to compute the activity coefficients of ions in electrolytes in 1925 (Hückel …