X Zhang, Y Wang, Y Wang, Y Guo, X Xie… - Chemical …, 2022 - pubs.rsc.org
Electrocatalytic nitrite reduction is of great significance for wastewater treatment and value- added chemicals synthesis. This review highlights the latest progress in electrochemical …
SL Meng, C Zhang, C Ye, JH Li, S Zhou… - Energy & …, 2023 - pubs.rsc.org
Herein, we demonstrate cobaloximes as a bioinspired molecular platform for exclusive ammonia synthesis via electrocatalytic NO2− reduction (eNO2− RR), which attained 98.5 …
The selective transformation of nitrogen compounds is a foundation of the modern chemical industry. Existing thermochemical processes largely rely on fossil fuels and innovating …
DR Pye, NP Mankad - Chemical Science, 2017 - pubs.rsc.org
Bimetallic catalysis represents an alternative paradigm for coupling chemistry that complements the more traditional single-site catalysis approach. In this perspective, recent …
TJ Mazzacano, NP Mankad - Journal of the American Chemical …, 2013 - ACS Publications
Heterobimetallic Cu–Fe and Zn–Fe complexes catalyze C–H borylation, a transformation that previously required noble metal catalysts. The optimal catalyst,(IPr) Cu-FeCp (CO) 2 …
The cobalt complex [CoIII N 4 H (Br) 2]+(N 4 H= 2, 12-dimethyl-3, 7, 11, 17-tetraazabicyclo- [11.3. 1]-heptadeca-1 (7), 2, 11, 13, 15-pentaene) was used for electrocatalytic CO2 …
The generation of metal hydride intermediates during reductive electrocatalysis in the presence of acid most commonly leads to the hydrogen evolution reaction (HER) …
Y Guo, JR Stroka, B Kandemir… - Journal of the …, 2018 - ACS Publications
A cobalt-tripeptide complex (CoGGH) is developed as an electrocatalyst for the selective six- electron, eight-proton reduction of nitrite to ammonium in aqueous buffer near neutral pH …
JR Stroka, B Kandemir, EM Matson, KL Bren - ACS Catalysis, 2020 - ACS Publications
Catalytic reduction of nitrite by an iron complex in water near neutral pH to form hydroxylamine and ammonium is reported. The catalyst is an iron center coordinated by the …