Restoring the nitrogen cycle by electrochemical reduction of nitrate: progress and prospects

Y Zeng, C Priest, G Wang, G Wu - Small Methods, 2020 - Wiley Online Library
The increasing amount of anthropogenic nitrogen has resulted in alarming levels of nitrate in
bodies of water and caused a cascade of damage to the environment and human health …

Recent advances in electrocatalytic nitrite reduction

X Zhang, Y Wang, Y Wang, Y Guo, X Xie… - Chemical …, 2022 - pubs.rsc.org
Electrocatalytic nitrite reduction is of great significance for wastewater treatment and value-
added chemicals synthesis. This review highlights the latest progress in electrochemical …

Cobaloximes: selective nitrite reduction catalysts for tandem ammonia synthesis

SL Meng, C Zhang, C Ye, JH Li, S Zhou… - Energy & …, 2023 - pubs.rsc.org
Herein, we demonstrate cobaloximes as a bioinspired molecular platform for exclusive
ammonia synthesis via electrocatalytic NO2− reduction (eNO2− RR), which attained 98.5 …

Regulation of the electrocatalytic nitrogen cycle based on sequential proton–electron transfer

D He, H Ooka, Y Li, Y Kim, A Yamaguchi, K Adachi… - Nature Catalysis, 2022 - nature.com
The selective transformation of nitrogen compounds is a foundation of the modern chemical
industry. Existing thermochemical processes largely rely on fossil fuels and innovating …

[HTML][HTML] Bimetallic catalysis for C–C and C–X coupling reactions

DR Pye, NP Mankad - Chemical Science, 2017 - pubs.rsc.org
Bimetallic catalysis represents an alternative paradigm for coupling chemistry that
complements the more traditional single-site catalysis approach. In this perspective, recent …

Base metal catalysts for photochemical C–H borylation that utilize metal–metal cooperativity

TJ Mazzacano, NP Mankad - Journal of the American Chemical …, 2013 - ACS Publications
Heterobimetallic Cu–Fe and Zn–Fe complexes catalyze C–H borylation, a transformation
that previously required noble metal catalysts. The optimal catalyst,(IPr) Cu-FeCp (CO) 2 …

Studies of Cobalt-Mediated Electrocatalytic CO2 Reduction Using a Redox-Active Ligand

DC Lacy, CCL McCrory, JC Peters - Inorganic chemistry, 2014 - ACS Publications
The cobalt complex [CoIII N 4 H (Br) 2]+(N 4 H= 2, 12-dimethyl-3, 7, 11, 17-tetraazabicyclo-
[11.3. 1]-heptadeca-1 (7), 2, 11, 13, 15-pentaene) was used for electrocatalytic CO2 …

Use of a PCET Mediator Enables a Ni-HER Electrocatalyst to Act as a Hydride Delivery Agent

J Derosa, P Garrido-Barros, M Li… - Journal of the American …, 2022 - ACS Publications
The generation of metal hydride intermediates during reductive electrocatalysis in the
presence of acid most commonly leads to the hydrogen evolution reaction (HER) …

Cobalt metallopeptide electrocatalyst for the selective reduction of nitrite to ammonium

Y Guo, JR Stroka, B Kandemir… - Journal of the …, 2018 - ACS Publications
A cobalt-tripeptide complex (CoGGH) is developed as an electrocatalyst for the selective six-
electron, eight-proton reduction of nitrite to ammonium in aqueous buffer near neutral pH …

Electrocatalytic multielectron nitrite reduction in water by an iron complex

JR Stroka, B Kandemir, EM Matson, KL Bren - ACS Catalysis, 2020 - ACS Publications
Catalytic reduction of nitrite by an iron complex in water near neutral pH to form
hydroxylamine and ammonium is reported. The catalyst is an iron center coordinated by the …