Thermally-induced spin-crossover (SCO) in Fe (4-ethynylpyrdine) 2 [Fe (CN) 5 NO]. Why is the SCO observed in 2D ferrous nitroprussides despite the NO–NC …

K Scanda, Y Avila, L Sánchez, R Mojica… - New Journal of …, 2023 - pubs.rsc.org
Pillared ferrous nitroprussides form an interesting series of coordination polymers where the
spin crossover (SCO) behavior has been observed for several pillar organic molecules. This …

Interpenetration Phenomena via Anion Template Effects in Fe (II) and Co (II) Coordination Networks with a Bis-(1, 2, 4-triazole) Ligand

DN Jordan, PG Straßburg, D Woschko, LM Carrella… - Polymers, 2023 - mdpi.com
Seven new coordination networks,[Fe (tbbt) 3](BF4) 2 (1),[Co (tbbt) 3](BF4) 2 (2),[Fe (tbbt)
3](ClO4) 2 (3),[Co (tbbt) 3](ClO4) 2 (4),[Fe (NCS) 2 (tbbt) 2](5),[Co (NCS) 2 (tbbt) 2](6), and …

Plasma-Engineered 2D Ni Nanoplates as Advanced Oxygen Evolution Reaction Electrocatalysts for Direct Seawater Electrolysis

S Kim, S Kim, Y Han, Y Kim, S Lee, J Yang… - ACS Applied Energy …, 2025 - ACS Publications
Hydrogen is crucial for achieving carbon neutrality and sustainable energy. To
commercialize water electrolysis technology, the development of high-performance OER …

Fe(L)2[M(CN)4] with L = 4-Ethyl Isonicotinate and M = Ni, Pd, Pt.─A Series of Hofmann-Type Frameworks with Spin Crossover: The Dominant Role of the Fe–NC …

MC Vázquez, JW Reid, Y Avila… - The Journal of …, 2024 - ACS Publications
This contribution reports the incorporation of an organic pillar (L), 4-ethyl isonicotinate,
between adjacent layers of the series of 2D coordination polymers, Fe [M (CN) 4], with M …

Crystal structures and properties of Fe(H2O)2[Ni(CN)4]·nH2O hydrates

L Torres, AA Lemus-Santana, L Sánchez… - Journal of …, 2023 - Taylor & Francis
We report the crystal structures and properties of iron hydrate compounds. These hydrates
have 2D topologies and crystallize with three different structural features depending on the …

Improving Mg2+ ionic conductivity in ZIF-8 by Cu (II) doping and mbIm incorporation into the framework

L Sánchez, P Acevedo-Peña, MÁ Aguilar-Frutis… - Solid State Ionics, 2024 - Elsevier
Transitioning to all-solid-state batteries and alternative technologies from liquid electrolyte
counterparts is a matter of security and sustainability. In this scenario, magnesium is a strong …

Understanding spin-dependent vibrational frequencies in Fe (II) metal organic coordination complexes

S Tae, AY Mohamed, K Kitase, T Kitazawa… - Current Applied …, 2024 - Elsevier
We investigated the compositional and temperature (T) dependences of vibrational
frequencies in Hofmann-type Fe (L) 2 [M (CN) 4] spin-crossover (SCO) coordination …

Single-Crystal Structure Analysis of Three Novel Iron(II) Coordination Polymers with Bridging 1,3,5-Tris((1H-1,2,4-triazol-1-yl)methyl)benzene

A Limon, DN Jordan, T Strothmann, LP Cuignet… - Crystals, 2023 - mdpi.com
Three novel iron (II) coordination polymers, namely [Fe (H2O) 2 (ttmb) 2](ClO4) 2· 4H2O
(1),[Fe (H2O) 2 (ttmb) 2](BF4) 2· 4H2O (2) and [Fe (NCS) 2 (ttmb) 2](3), were synthesized …