The chemistry of binuclear palladium (II) and platinum (II) complexes has been reviewed.
This review deals with complexes derived from various classes of ligands and covers …

The chemistry of discrete molecular chains constituted by metals in low oxidation states,
displaying metal–metal proximity and stabilized by suitable metal-bridging, assembling …

The numerous chemical, physical, and biological properties of organotin compounds have
largely contributed to the development of fundamental synthetic, structural, and reactivity …

Heterobinuclear catalysts capable of bimetallic cooperative bond activation provide an
alternative pathway to approach the discovery of novel and unique reactivity and selectivity …

Transition-metal chemistry is currently one of the most rapidly developing research areas.
From Hein's discovery in 1941 of the first metal silicon complex, followed by Wilkinson's Cp …

The “short-bite” ligands CH 2 (PR 2) 2 or CH (PR 2) 3 (R= Me, Ph), RN (PX 2) 2 (R= H, Me,
Et; X= F, OR′(R′= Me, Et, i-Pr, Ph), Ph), RE (CH 2 ER 2) 2 (E= P, As; R= Me, Ph), Ph 2 P (2 …

The triorganotin halides (Cab C, P) SnMe2X (2a, X= Cl; 2b, X= Br) and a tetraorganotin
compound (Cab C, P) SnMe3 (7), containing the o-carboranylphosphino ligand (Cab C, P) …

Heterobimetallic complexes [(OC) 3 (R3Si) Fe (μ-dppm) Pd (η3-allyl)] 1 (R= OMe, Me,
OSiMe3, OSi (H) Me2) and [(OC) 3Fe {μ-Si (OR) 2 (OR)}(μ-dppm) PdCl] 6 (R= Me, SiMe3) …

The σ-bis and tetraalkynyl anions [cis-Pt (C6F5) 2 (C⋮ CR) 2] 2-and [Pt (C⋮ CR) 4] 2-(R= Ph,
tBu, SiMe3) have been shown to be useful reagents for the formation of bis (μ-alkynyl) …

Metal-silicon single or multiple bonds are key functionalities in a number of important
catalytic transformations, such as the hydrosilylation of alkenes and alkynes and the …