Circular dichroism sensing: Strategies and applications

JSSK Formen, JR Howard, EV Anslyn… - Angewandte Chemie …, 2024 - Wiley Online Library
The analysis of the absolute configuration, enantiomeric composition, and concentration of
chiral compounds are frequently encountered tasks across the chemical and health …

Porphyrin cage compounds based on glycoluril–from enzyme mimics to functional molecular machines

JAAW Elemans, RJM Nolte - Chemical Communications, 2019 - pubs.rsc.org
The study of artificial receptor molecules with the intention to mimic enzyme–substrate
binding processes and catalysis in nature has always been a traditional area of research in …

Optical analysis of reaction yield and enantiomeric excess: a new paradigm ready for prime time

BT Herrera, SL Pilicer, EV Anslyn… - Journal of the …, 2018 - ACS Publications
This Perspective highlights the advances of optical methods for asymmetric reaction
discovery. Optical analysis allows for the determination of absolute configuration …

Molecular Recognition and Chirality Sensing of Epoxides in Water Using Endo-Functionalized Molecular Tubes

LL Wang, Z Chen, WE Liu, H Ke… - Journal of the …, 2017 - ACS Publications
Chiral epoxides are important intermediates in chemistry and biology. The high-throughput
screening of asymmetric epoxidation conditions requires fast determination of the absolute …

A Self‐Assembled Cage for Wide‐Scope Chiral Recognition in Water

G Wu, Y Chen, S Fang, L Tong, L Shen… - Angewandte Chemie …, 2021 - Wiley Online Library
Herein, we report the self‐assembly of an anionic homochiral octahedral cage by
condensing six Ga3+ cations and four trisacylhydrazone ligands. The robust nature of the …

A Liquid–Liquid Interfacial Strategy for Construction of Electroactive Chiral Covalent–Organic Frameworks with the Aim to Enlarge the Testing Scope of Chiral …

F Wang, W Cai, L Tan, J Li, D Wu, Y Kong - Analytical Chemistry, 2024 - ACS Publications
Although electroactive chiral covalent–organic frameworks (CCOFs) are considered an ideal
platform for chiral electroanalysis, they are rarely reported due to the difficult selection of …

Fluorescence detected circular dichroism (FDCD) for supramolecular host–guest complexes

A Prabodh, Y Wang, S Sinn, P Albertini, C Spies… - Chemical …, 2021 - pubs.rsc.org
Fluorescence-detected circular dichroism (FDCD) spectroscopy is applied for the first time to
supramolecular host–guest and host–protein systems and compared to the more known …

Cyclic metalloporphyrin dimers: Conformational flexibility, applications and future prospects

P Mondal, SP Rath - Coordination Chemistry Reviews, 2020 - Elsevier
Over the past few decades, cyclic metalloporphyrin dimers have been significantly exploited
in the fields of molecular motion, switches, recognition, biomimetic chemistry, and …

Absolute stereochemical determination of organic molecules through induction of helicity in host–guest complexes

H Gholami, D Chakraborty, J Zhang… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Stereochemistry is a fundamental molecular property with important
ramifications for structure, function, and activity of organic molecules. The basic building …

Supramolecular chirogenesis induced by platinum (II) tweezers with excellent environmental tolerance

M Liu, Y Han, H Zhong, X Zhang… - Angewandte Chemie …, 2021 - Wiley Online Library
Supramolecular chirogenesis has emerged as an effective strategy to access symmetry
breaking in artificial systems. However, the chirogenic signals suffer from high susceptibility …