Pyridines are among the most prevalent heterocyclic structural units in pharmaceutical and
agrochemical targets, as well as in materials science (Figure 1). 1 Pyridines also provide …

The cation− π interaction is an attractive noncovalent interaction between a cation and a π
system. Due to the stronger interaction energy than those of the other π interactions, such as …

This review provides a comprehensive compilation of available literature concerning the
synthesis of 1, 2-dihydropyridines. The most important recent developments and concepts …

As part of a program directed at studying the synthesis and synthetic utility of chiral
dihydropyridones, 1 we are investigating annulation reactions of N-acyl-2, 3-dihydro-4 …

A series of β-amino alcohols, conveniently prepared from limonene oxide, were evaluated
as catalysts for the enantioselective addition of dialkylzinc to benzaldehyde. These limonene …

The oxidative dimerization of glycinates 1 with iodine takes place under kinetic control. The
stereochemistry of the resulting 3-aminoaspartate 3 depends on the method used …

Cohalogenation of (R)-limonene and (R)-carvomenthene with I2/H2O/Cu (OAc) 2· H 2O in
aqueous dioxane followed by base treatment produced stereospecifically the corresponding …

Rhodium (II)-or acid-mediated decomposition of 2-diazo-2-phenylacetates of chiral alcohols
in the presence of various hydroxylic compounds (ROH) results in the diastereoselective …

CrIII(salen) catalysed asymmetric ring opening of monocyclic terpene-epoxides -
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摘要研究了在过渡金属配合物催化下α-重氮-β-二羰基化合物与醇的插入反应,
考察了重氮化合物的结构, 醇的结构, 催化剂的性质, 反应溶剂和反应温度对这一反应的影响 …