The many flavours of mechanochemistry and its plausible conceptual underpinnings

RT O'Neill, R Boulatov - Nature Reviews Chemistry, 2021 - nature.com
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …

DNA walkers for biosensing development

L Song, Y Zhuge, X Zuo, M Li, F Wang - Advanced Science, 2022 - Wiley Online Library
The ability to design nanostructures with arbitrary shapes and controllable motions has
made DNA nanomaterials used widely to construct diverse nanomachines with various …

Toughening hydrogels through force-triggered chemical reactions that lengthen polymer strands

Z Wang, X Zheng, T Ouchi, TB Kouznetsova, HK Beech… - Science, 2021 - science.org
The utility and lifetime of materials made from polymer networks, including hydrogels,
depend on their capacity to stretch and resist tearing. In gels and elastomers, those …

The role of polymer mechanochemistry in responsive materials and additive manufacturing

MA Ghanem, A Basu, R Behrou, N Boechler… - Nature Reviews …, 2021 - nature.com
The use of mechanical forces to chemically transform polymers dates back decades. In
recent years, the use of mechanochemistry to direct constructive transformations in polymers …

Azobenzene as a photoswitchable mechanophore

Y Li, B Xue, J Yang, J Jiang, J Liu, Y Zhou, J Zhang… - Nature Chemistry, 2024 - nature.com
Azobenzene has been widely explored as a photoresponsive element in materials science.
Although some studies have investigated the force-induced isomerization of azobenzene …

Future‐oriented advanced diarylethene photoswitches: from molecular design to spontaneous assembly systems

HB Cheng, S Zhang, E Bai, X Cao, J Wang… - Advanced …, 2022 - Wiley Online Library
Diarylethene (DAE) photoswitch is a new and promising family of photochromic molecules
and has shown superior performance as a smart trigger in stimulus‐responsive materials …

Mechanochemical degradation and recycling of synthetic polymers

J Zhou, TG Hsu, J Wang - Angewandte Chemie, 2023 - Wiley Online Library
The accumulation of plastic waste, due to lack of recycling, has led to serious environmental
pollution. Although mechanical recycling can alleviate this issue, it inevitably reduces the …

Validation of the CoGEF method as a predictive tool for polymer mechanochemistry

IM Klein, CC Husic, DP Kovács… - Journal of the …, 2020 - ACS Publications
The development of force-responsive molecules called mechanophores is a central
component of the field of polymer mechanochemistry. Mechanophores enable the design …

Harnessing the power of force: development of mechanophores for molecular release

BA Versaw, T Zeng, X Hu, MJ Robb - Journal of the American …, 2021 - ACS Publications
Polymers that release small molecules in response to mechanical force are promising
materials for a variety of applications ranging from sensing and catalysis to targeted drug …

Recent progress in the development of molecular-scale electronics based on photoswitchable molecules

X Huang, T Li - Journal of Materials Chemistry C, 2020 - pubs.rsc.org
Molecular electronic devices with tunable conductance states show great potential in
building memories and logic components for next-generation circuits. In recent years …