In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Hydrogen-atom transfer (HAT) provides straightforward methods to generate open-shell
radical intermediates from RH (R= C, Si, etc.) bonds and offers unique opportunities for …

The selective functionalization of alkanes has long been recognized as a prominent
challenge and an arduous task in organic synthesis. Hydrogen atom transfer (HAT) …

The efficient conversion of a C–H bond in the polyether chain to other functional groups
provides great opportunities for development of novel applications in many research fields …

The value of catalytic dehydrogenation of aliphatics (CDA) in organic synthesis has
remained largely underexplored. Known homogeneous CDA systems often require the use …

Using the power of light to drive controlled radical polymerizations has provided significant
advances in synthesis of well-defined polymers. Photoinduced atom transfer radical …

Degradable vinyl polymers by radical ring‐opening polymerization are promising solutions
to the challenges caused by non‐degradable vinyl plastics. However, achieving even …

Introducing functionality onto PE surfaces is a longstanding challenge in polymer science,
driven by the need for polymer materials with improved adhesion and antifouling properties …

Organocatalyzed reversible‐deactivation radical polymerizations (RDRPs) are attractive for
many applications. Here, we developed photoredox‐mediated RDRP by activating (hetero) …