Ligand-based redox: catalytic applications and mechanistic aspects
For the last few decades, coordination chemists have seen many ligands whose role
pervades far beyond being a supporting ancillary. The ambiguity in their electronic structure …
pervades far beyond being a supporting ancillary. The ambiguity in their electronic structure …
Design and synthesis of a solution-processed redox-active bis (formazanate) zinc complex for resistive switching applications
In this paper, we report the synthesis and characterization of a mononuclear zinc complex
(1) containing a redox-active bis (4-antipyrinyl) derivative of the 3-cyanoformazanate ligand …
(1) containing a redox-active bis (4-antipyrinyl) derivative of the 3-cyanoformazanate ligand …
Exclusively Ligand-Redox-Promoted C–H Tertiary Alkylation of Heteroarenes
Herein, we describe a predominant role of the redox-active formazanate ligand backbone in
steering base metal iron catalysis. The iron complex of the chosen formazanate ligand …
steering base metal iron catalysis. The iron complex of the chosen formazanate ligand …
Multielectron Redox Afforded by a Pincer Ligand Promoting Kumada Cross‐Coupling Reactions
The redox‐active nature of a pincer has been exploited to conduct C− C cross‐coupling
reactions under mild conditions. A nickel complex with a NNN pincer was dimeric in the solid …
reactions under mild conditions. A nickel complex with a NNN pincer was dimeric in the solid …
Visible‐Light‐Mediated Synthesis of α‐Ketoamides via Oxidative Amination of 2‐Bromoacetophenones Using Eosin Y as a Photoredox Catalyst
K Kishor, NS Prabhakar… - Chemistry–An Asian …, 2023 - Wiley Online Library
An oxidative amination of 2‐bromoacetophenones has been accomplished to provide α‐
ketoamides by using photoredox catalysis with air as oxidant. The reactants are readily …
ketoamides by using photoredox catalysis with air as oxidant. The reactants are readily …
Brook-Oxidation Reaction of Acylsilanes: General Access to α-Ketoamides and α-Ketothioamides
DN Yang, YN Du, P Wang, MY Han - Organic Letters, 2024 - ACS Publications
A novel chemoselective Brook-oxidation reaction of acylsilanes initiated by the carbamoyl
anion has been successfully developed for the first time. This method enables the synthesis …
anion has been successfully developed for the first time. This method enables the synthesis …
Heavy Alkaline–Earth Metal Formazanate Complexes and Their Catalytic Applications
D Jin, X Sun, PW Roesky - Organometallics, 2023 - ACS Publications
The synthesis and characterization of three alkaline–earth metal complexes comprising
formazanate ligands are described. Transamination between the neutral formazan [PhNNC …
formazanate ligands are described. Transamination between the neutral formazan [PhNNC …