The renaissance of non‐aqueous uranium chemistry

ST Liddle - Angewandte Chemie International Edition, 2015 - Wiley Online Library
Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

State of the art and perspectives in catalytic processes for CO2 conversion into chemicals and fuels: The distinctive contribution of chemical catalysis and …

M Aresta, A Dibenedetto, E Quaranta - Journal of Catalysis, 2016 - Elsevier
The need to reduce the emission of carbon dioxide into the atmosphere is pushing toward
the use of “renewable carbon”, so to avoid as much as possible burning “fossil carbon”. It …

Oxygen‐containing amorphous cobalt sulfide porous nanocubes as high‐activity electrocatalysts for the oxygen evolution reaction in an alkaline/neutral medium

P Cai, J Huang, J Chen, Z Wen - Angewandte Chemie, 2017 - Wiley Online Library
A novel OER electrocatalyst, namely oxygen‐incorporated amorphous cobalt sulfide porous
nanocubes (A‐CoS4. 6O0. 6 PNCs), show advantages over the benchmark RuO2 catalyst in …

Efficient Homogeneous Catalysis in the Reduction of CO2 to CO

DS Laitar, P Müller, JP Sadighi - Journal of the American …, 2005 - ACS Publications
The well-defined copper (I) boryl complex [(IPr) Cu (Bpin)][where IPr= 1, 3-bis (2, 6-
diisopropylphenyl) imidazol-2-ylidene, and pin= pinacolate: 2, 3-dimethyl-2, 3 …

Towards uranium catalysts

AR Fox, SC Bart, K Meyer, CC Cummins - Nature, 2008 - nature.com
The forefront of research into the complexes of uranium reveals chemical transformations
that challenge and expand our view of this unique element. Certain ligands form multiple …

Molecular approaches to the electrochemical reduction of carbon dioxide

C Finn, S Schnittger, LJ Yellowlees… - Chemical …, 2012 - pubs.rsc.org
This article reviews recent progress in the exploitation of carbon dioxide as a chemical
feedstock. In particular, the design and development of molecular complexes that can act as …

Small molecule activation by uranium tris (aryloxides): experimental and computational studies of binding of N2, coupling of CO, and deoxygenation insertion of CO2 …

SM Mansell, N Kaltsoyannis… - Journal of the American …, 2011 - ACS Publications
Previously unanticipated dinitrogen activation is exhibited by the well-known uranium tris
(aryloxide) U (ODtbp) 3, U (OC6H3-But2-2, 6) 3, and the tri-tert-butyl analogue U (OTtbp) 3 …

Metal–ligand multiple bonding in uranium: structure and reactivity

TW Hayton - Dalton Transactions, 2010 - pubs.rsc.org
There is a growing interest in uranium coordination chemistry, particularly as it relates to
metal–ligand multiple bonding, and in the last decade significant progress has been made …

Reductive cyclotrimerization of carbon monoxide to the deltate dianion by an organometallic uranium complex

OT Summerscales, FGN Cloke, PB Hitchcock… - Science, 2006 - science.org
Despite the long history of the Fischer-Tropsch reaction, carbon monoxide has proven
remarkably resistant to selective homologation under mild conditions. Here, we find that an …

Carbon dioxide activation with sterically pressured mid-and high-valent uranium complexes

SC Bart, C Anthon, FW Heinemann, E Bill… - Journal of the …, 2008 - ACS Publications
Sterically pressured mid-to high-valent uranium complexes with an aryloxide substituted
triazacyclononane ligand scaffold,[((RArO) 3tacn) 3–], were studied for carbon dioxide …