This review covers the use of 2-azaallyl anions, 2-azaallyl cations, and 2-azaallyl radicals in
organic synthesis up through June 2018. Particular attention is paid to both foundational …

Pyrroloindolines are important and privileged polycyclic indoline motifs that are widely
present in natural products and bio-significant molecules. From an organic chemistry …

The element nitrogen is essential to life. Considerable attention is thus paid to the
development of synthetic methods for its introduction into molecules. Nitrenes, long …

Fused polycyclic indoline skeletons are found in many natural products and bioactive
molecules. Several approaches, including dearomative cyclization of functionalized indoles …

Advanced tools for developing new functional materials and applications in chemical
research, pharmaceuticals, and materials science Cycloadditions are among the most useful …

Cobalt (II)-based metalloradical catalysis has been successfully applied to radical
bicyclization of allyl azidoformates to construct aziridine/oxazolidinone-fused bicyclic …

Catalyst-controlled divergent intermolecular cycloadditions of vinylaziridines with alkynes
have been developed. By using [Rh (NBD) 2] BF4 as the catalyst, a [3+ 2] cycloaddition …

The unique structure and reactivity of the aziridine ring has attracted the interest of organic
chemists for many years. Of these, the cycloaddition of alkynes with aziridines via C–C bond …

The first Lewis acid catalyzed [3+ 2] annulation of indoles and 2-aryl-N-tosylaziridines was
realized by using copper (I)/chiral diphosphine complexes as a catalyst. With this method, a …

Epoxidized polybutadiene and epoxidized polynorbornene were subjected to pulsed
ultrasound in the presence of small molecules capable of being trapped by carbonyl ylides …