Solid-state NMR spectroscopy is a powerful technique for the characterization of the atomic-
level structure and dynamics of materials. Nevertheless, the use of this technique is often …

Dynamic nuclear polarization (DNP) is one of the most prominent methods of sensitivity
enhancement in nuclear magnetic resonance (NMR). Even though solid-state DNP under …

Alkanes are the foremost basic energy sources and represent an important basic chemical
material for industrial applications. Highly efficient activation of C–H bonds can convert …

The field of Surface Organometallic Chemistry (SOMC) aims to blend the positive attributes
of homogeneous and heterogeneous catalysis. Significant insight into heterogeneous …

Understanding heterogeneous catalysts is a challenging pursuit due to surface site
nonuniformity and aperiodicity in traditionally used materials. One example is sulfated metal …

Catalytic C–H borylation is an attractive method for the conversion of the most abundant
hydrocarbon, methane (CH4), to a mild nucleophilic building block. However, existing CH4 …

A series of supported electrophilic organoruthenium complexes has been synthesized via
surface organometallic chemistry (SOMC) techniques and applied to the selective …

Well-defined organometallics supported on high surface area oxides are promising
heterogeneous catalysts. An important design factor in these materials is how the metal …

Sulfated zirconia (SZ) and its modified versions attract great interest in recent years,
because of their promising potential in n‐alkane isomerization. The oxidative and …

In this work, we present a novel series of oxide-supported Ir-ligand single-atom catalysts
(SACs) for ethylene hydrogenation. The SACs were created by a metal–ligand self …