Redox reactions play important roles in almost all biological processes, including
photosynthesis and respiration, which are two essential energy processes that sustain all life …

One of the hallmark advances in our understanding of metalloprotein function is showcased
in our ability to design new, non-native, catalytically active protein scaffolds. This review …

The 6th edition of this classic comprises the most comprehensive guide to infrared and
Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds …

Protein design is a valuable tool for understanding the fundamental factors that dictate
protein structure and function. The field of protein design has seen significant progress over …

The period covered by this document is from the beginning of 1995 through late 1997. The
most recent comprehensive review of this topic appeared in 1994 (1) and covered late 1991 …

Cytochrome c oxidases, or more generally hemecopper oxidases (see section 2), have for a
considerable time attracted the interest of modeling chemists. This is due to the importance …

The authors describe basic theoretical concepts of vibrational spectroscopy, address
instrumental aspects and experimental procedures, and discuss experimental and …

Using a combination of electronic spectroscopies, electronic structural descriptions have
been developed for a series of binuclear CuA-type centers in Bacillus subtilis C c O and …

The experimentally determined electronic structures of mononuclear blue Cu and binuclear
CuA centers are summarized and their relation to intraand inter-protein electron transfer (ET) …

This review traces the history of understanding of the CUA, site in cytochrome c oxidase
(COX) from the beginnings, when few believed that there was any significant Cu in COX, to …