To each his own: isonitriles for all flavors. Functionalized isocyanides as valuable tools in organic synthesis

M Giustiniano, A Basso, V Mercalli… - Chemical Society …, 2017 - pubs.rsc.org
The term functionalized isocyanides refers to all those isocyanides in which a neighbouring
functional group can finely tune the reactivity of the isocyano group or can be exploited in …

Still unconquered: enantioselective Passerini and Ugi multicomponent reactions

Q Wang, DX Wang, MX Wang, J Zhu - Accounts of chemical …, 2018 - ACS Publications
Conspectus The Passerini three-component (P-3CR) and the Ugi four-component (U-4CR)
are two of the most prominent isocyanide-based multicomponent reactions (IMCRs). The P …

An efficient nanoscale heterogeneous catalyst for the capture and conversion of carbon dioxide at ambient pressure

XH Liu, JG Ma, Z Niu, GM Yang… - Angewandte Chemie, 2015 - Wiley Online Library
Silver nanoparticles were successfully supported on the zeolite‐type metal–organic
framework MIL‐101 to yield Ag@ MIL‐101 by a simple liquid impregnation method. For the …

Isocyanoacetate derivatives: synthesis, reactivity, and application

AV Gulevich, AG Zhdanko, RVA Orru… - Chemical …, 2010 - ACS Publications
Isocyanide (isonitrile) chemistry began in 1859 when Lieke obtained the first compound of
this type. 1 In 1958, isocyanides became generally available by dehydration of formamides …

The Ugi three-component reaction and its variants

JC Flores-Reyes, A Islas-Jácome… - Organic Chemistry …, 2021 - pubs.rsc.org
More than 60 years have passed since I. Ugi synthesized the first α-amidoamides in one
experimental step involving a combination of aldehydes, amines, carboxylic acids and …

Heterocycles as key substrates in multicomponent reactions: the fast lane towards molecular complexity

N Isambert, R Lavilla - Chemistry–A European Journal, 2008 - Wiley Online Library
Heterocycles display an intrinsic reactivity which enables rich, versatile and productive
transformations. Taking into account their ubiquitous presence in natural products and …

Catalytic Divergent Synthesis of 3H or 1H Pyrroles by [3 + 2] Cyclization of Allenoates with Activated Isocyanides

JY Liao, PL Shao, Y Zhao - Journal of the American Chemical …, 2015 - ACS Publications
The cyclization of allenoates with activated isocyanides was reported for the first time. While
Ag catalysis led to an unprecedented enantioselective synthesis of 3 H pyrroles, a simple …

Beyond the Ugi reaction: less conventional interactions between isocyanides and iminium species

L El Kaim, L Grimaud - Tetrahedron, 2009 - Elsevier
The history of isocyanide chemistry goes back to the first synthesis of allyl isocyanide by
alkylation of silver cyanide reported by Lieke in 1859. 1 These isomers of cyanides …

Intermolecular and Selective Synthesis of 2, 4, 5‐Trisubstituted Oxazoles by a Gold‐Catalyzed Formal [3+ 2] Cycloaddition

PW Davies, A Cremonesi, L Dumitrescu - Angewandte Chemie, 2011 - infona.pl
Oxazols neue Welt: Gold‐katalysierte intermolekulare Reaktionen von Pyridin‐N‐aminiden
mit Inamiden führen zu trisubstituierten 1, 3‐Oxazolen mit einer Vielzahl von funktionellen …

Carboxylation of terminal alkynes with carbon dioxide catalyzed by poly (N‐heterocyclic carbene)‐supported silver nanoparticles

D Yu, MX Tan, Y Zhang - Advanced Synthesis & Catalysis, 2012 - Wiley Online Library
An N‐heterocyclic carbene (NHC) polymer supported silver nanoparticle catalyst system
was developed. The novel nano‐composite catalyst demonstrated very high activity and …