Deuterium kinetic isotope effects as redox mechanistic criterions
S Fukuzumi, YM Lee, W Nam - Bulletin of the Korean Chemical …, 2021 - Wiley Online Library
This account article focuses on deuterium kinetic isotope effects (KIEs) used as criterions to
elucidate redox mechanisms including proton‐, hydrogen‐and hydride‐transfer reactions …
elucidate redox mechanisms including proton‐, hydrogen‐and hydride‐transfer reactions …
C–H bond cleavage by bioinspired nonheme metal complexes
The functionalization of C–H bonds is one of the most challenging transformations in
synthetic chemistry. In biology, these processes are well-known and are achieved with a …
synthetic chemistry. In biology, these processes are well-known and are achieved with a …
Inspiration from Nature: influence of engineered ligand scaffolds and auxiliary factors on the reactivity of biomimetic oxidants
Enzymes are highly efficient catalysts in Nature that often react with high stereo-, chemo-,
and regioselectivity. Usually, enzymes achieve this selectivity through substrate binding and …
and regioselectivity. Usually, enzymes achieve this selectivity through substrate binding and …
Stereoelectronic Tuning of Bioinspired Nonheme Iron (IV)-Oxo Species by Amide Groups in Primary and Secondary Coordination Spheres for Selective Oxygenation …
Two mononuclear iron (II) complexes,[(6-amide2-BPMEN) FeII](OTf) 2 (1) and [(6-amide-Me-
BPMEN) FeII (OTf)](OTf)(2), supported by two BPMEN-derived (BPMEN= N 1, N 2-dimethyl …
BPMEN) FeII (OTf)](OTf)(2), supported by two BPMEN-derived (BPMEN= N 1, N 2-dimethyl …
Selective oxidation of active site aromatic residues in engineered Cu proteins
Recent studies have revealed critical roles for the local environments surrounding
metallocofactors, such as the newly identified CuD site in particulate methane …
metallocofactors, such as the newly identified CuD site in particulate methane …
Impact of carboxylate ligation on the C–H activation reactivity of a non-heme Fe (IV) O complex: a computational investigation
A Katoch, D Mandal - Dalton Transactions, 2024 - pubs.rsc.org
A comprehensive DFT investigation has been presented to predict how a carboxylate-rich
macrocycle would affect the reactivity of a non-heme Fe (IV) O complex towards C–H …
macrocycle would affect the reactivity of a non-heme Fe (IV) O complex towards C–H …
Cooperative Co-Activation of Water and Hypochlorite by a Non-Heme Diiron (III) Complex
Aqueous solutions of the iron (III) complex of N, N, N′-tris (2-pyridylmethyl)
ethylenediamine-N′-acetate (tpena) react with hypochlorite (ClO–) to produce the reactive …
ethylenediamine-N′-acetate (tpena) react with hypochlorite (ClO–) to produce the reactive …
Application of high valent iron stabilized by a biomimetic carboxylato-containing ligand for aqueous contaminant removal
J Xie - 2022 - unsworks.unsw.edu.au
The utilization of non-heme iron oxo complexes holds promise of a new generation of
contaminant remediation technologies. These biomimetic complexes are efficient and …
contaminant remediation technologies. These biomimetic complexes are efficient and …
Bispidin-basierte Kupfer-und Eisennitrenkomplexe Charakterisierung, mechanistische Studien, katalytische Anwendung
T Josephy - 2022 - archiv.ub.uni-heidelberg.de
In dieser Arbeit wurde eine Reihe neuartiger Bispidin-basierter Kupfer-und
Eisennitrenkomplexe synthetisiert, charakterisiert und hinsichtlich ihrer katalytischen …
Eisennitrenkomplexe synthetisiert, charakterisiert und hinsichtlich ihrer katalytischen …
Modelling the coordination environment in α‐ketoglutarate dependent oxygenases–a comparative study on the effect of N‐vs. O‐ligation
K Warm, D Kass, M Haumann, H Dau… - … für anorganische und …, 2022 - Wiley Online Library
In various non‐heme iron oxygenases the Fe (II) center is coordinated by 2 N and 1 O atoms
of the 2‐His‐2‐carboxylate facial triad; however, most artificial model complexes bear only N …
of the 2‐His‐2‐carboxylate facial triad; however, most artificial model complexes bear only N …