N, N, N′, N'-tetramethyl diglycolamide (TMDGA), a methylated variant of the diglycolamide
extractants being proposed as curium holdback reagents in advanced used nuclear fuel …

Radiometals are increasingly used in nuclear medicine for both diagnostic and therapeutic
purposes. The DOTA ligand (1, 4, 7, 10-tetraazacyclododecane-1, 4, 7, 10-tetraacetic acid) …

Radiolytic degradation is an important aspect to consider when developing a ligand or a
complexant for radionuclides. Diglycolamide extractants (DGAs) have been playing an …

The impact of trivalent lanthanide ion complexation and temperature on the chemical
reactivity of N, N, N′, N′-tetraoctyl diglycolamide (TODGA) with the n-dodecane radical …

Deciphering the solution chemistry and speciation of actinides is inherently difficult due to
radioactivity, rarity, and cost constraints, especially for transplutonium elements. In this …

The mechanism by which high concentrations (1.5 M in n-dodecane) of N, N-di-2-ethylhexyl-
isobutyramide (DEHiBA) extracts HNO3 and UO2 (NO3) 2 is under examination. Most prior …

Despite the significant impact of radiation-induced redox reactions on the accessibility and
lifetimes of actinide oxidation states, fundamental knowledge of aqueous actinide metal ion …

The study investigated• OH-derived radicals from certain organic acids employed in nuclear
fuel processing and separation using EPR spectroscopy and quantum chemistry methods …

A systematic study of the impact on the chemical reactivity of the oxidising n-dodecane
radical cation (RH˙+) with f-element complexed 2-ethylhexylphosphonic acid mono-2 …

Radiation-induced ligand destruction and concomitant degradation product formation is
unavoidable under envisioned used nuclear fuel reprocessing conditions, and ultimately …