Photodissociation Dynamics of Vinoxy Radical via the B̃2A″ State: The H + CH2CO Product Channel

G Sun, X Zheng, K Xu, Y Song… - The Journal of Physical …, 2021 - ACS Publications
Photodissociation dynamics of the jet-cooled vinoxy radical (CH2CHO) via the B̃2A ″state
was studied in the near-ultraviolet (near-UV) region of 308–328 nm using high-n Rydberg H …

Multiple dehydrogenation of fluorene cation and neutral fluorene using the statistical molecular fragmentation model

P Désesquelles, NT Van-Oanh, L Xu, Y Luo… - Physical Chemistry …, 2021 - pubs.rsc.org
The statistical molecular fragmentation (SMF) model was used to analyze the 306
fragmentation channels (containing 611 different species) that result from the fluorene …

H-atom and O-atom methods: from balancing redox reactions to determining the number of transferred electrons

PK Yuen, CMD Lau - Chemistry Teacher International, 2022 - degruyter.com
Defining and balancing redox reaction requires both chemical knowledge and mathematical
skills. The prevalent approach is to use the concept of oxidation number to determine the …

Photodissociation of the trichloromethyl radical: photofragment imaging and femtosecond photoelectron spectroscopy

CT Matthaei, DP Mukhopadhyay, A Röder… - Physical Chemistry …, 2022 - pubs.rsc.org
Halogen-containing radicals play a key role in catalytic reactions leading to stratospheric
ozone destruction, thus their photochemistry is of considerable interest. Here we investigate …

The statistical molecular fragmentation model compared to experimental plasma induced hydrocarbon decays

P Désesquelles, S Pasquiers, N Blin-Simiand… - Physical Chemistry …, 2020 - pubs.rsc.org
We compare the predictions of our recently developed statistical molecular fragmentation
(SMF) model with experimental results from plasma induced hydrocarbon decay. The SMF …

Two-photon dissociation dynamics of hydroxyl radical

G Sun, X Zheng, Y Qin, Y Song, J Zhang… - Chinese Journal of …, 2020 - pubs.aip.org
Two-photon dissociation dynamics of the OH radical is studied using the high-n Rydberg
atom time-of-flight (HRTOF) technique. The H (2S)+ O (1D) and H (2S)+ O (1S) product …

Gas Phase Synthesis of the Elusive Trisilacyclopropyl Radical (Si3H5) via Unimolecular Decomposition of Chemically Activated Doublet Trisilapropyl Radicals (Si3H7 …

S Doddipatla, Z Yang, AM Thomas… - The Journal of …, 2020 - ACS Publications
The gas phase reaction of the simplest silicon-bearing radical silylidyne (SiH; X2Π) with
disilane (Si2H6; X1A1g) was investigated in a crossed molecular beams machine …